Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (7): 755.
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Lin Zhanru1, Gonsalves. K.2
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Abstract: Monomers, 1, 1'-bis(β-aminoethyl) ferrocene (1) and 1,1,-bis (β-hydro-xyethyl) ferrocene were synthesized starting frpm ferrocene via acetylation, hydrolysis, esterification, cyanidation and reduction, yields obtained were 73% and 98%, respectively. Monomer (1) then, reacted with diacid chlorides as well as with diisocyanates, and monomer (2) reacted with terephthaloyl chloride, leading to ferrocene-containing polyamides, polyureas and polyesters in their backbones under the interfacial polymerization condition.TGanalysis of the ferrocene-containing polyamide, in contrast, with the poly urea and polyester, showed weight loss only 1.0 to 1.5% at 300℃ and 3.0 to 6.0% at 400℃, respectively.
Key words: Interfacial Polymerization technique, Addition Bace, Thermostability
TrendMD:
Lin Zhanru, Gonsalves. K.. Synthesis of Ferrocene-Containing Poiyanlides, Polyureas and Polyesters in Their Backbones by the Interfacial Technique[J]. Chem. J. Chinese Universities, 1988, 9(7): 755.
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http://www.cjcu.jlu.edu.cn/EN/Y1988/V9/I7/755