Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (7): 755.

• Articles • Previous Articles    

Synthesis of Ferrocene-Containing Poiyanlides, Polyureas and Polyesters in Their Backbones by the Interfacial Technique

Lin Zhanru1, Gonsalves. K.2   

  1. 1. Department of Chemistry, Sichuan Normal University, Chengdu;
    2. University of Massachusetts, U. S. A.
  • Received:1987-01-17 Online:1988-07-24 Published:1988-07-24

Abstract: Monomers, 1, 1'-bis(β-aminoethyl) ferrocene (1) and 1,1,-bis (β-hydro-xyethyl) ferrocene were synthesized starting frpm ferrocene via acetylation, hydrolysis, esterification, cyanidation and reduction, yields obtained were 73% and 98%, respectively. Monomer (1) then, reacted with diacid chlorides as well as with diisocyanates, and monomer (2) reacted with terephthaloyl chloride, leading to ferrocene-containing polyamides, polyureas and polyesters in their backbones under the interfacial polymerization condition.TGanalysis of the ferrocene-containing polyamide, in contrast, with the poly urea and polyester, showed weight loss only 1.0 to 1.5% at 300℃ and 3.0 to 6.0% at 400℃, respectively.

Key words: Interfacial Polymerization technique, Addition Bace, Thermostability

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