Studies on Thermokinetics (Ⅵ)——Thermokinetics for Ring-Opening Reaction of the Epichlorohydrin

Abstract

Abstract: On the theoretical basis of thermokinetics proposed in previous articles, the thermokinetics for ring-opening reaction of the epichlorohydrin with potassium iodide has been studied at 20℃ in buffer solution with the method of dimension-less parameter for the second order reaction. The reproducibility of experimental results is very good, and the rate constant is in fair agreement with the values in literature.The influences of the concentration and pHvalues of the buffer solution on the rate constant of measured reaction have been also discussed.

Key words: Thermokinetics, Ring-opening, Buffer solution, Reproducibility

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Huang Qizhong, Zhang Yuanqin, Zeng Xiancheng. Studies on Thermokinetics (Ⅵ)——Thermokinetics for Ring-Opening Reaction of the Epichlorohydrin[J]. Chem. J. Chinese Universities, 1988, 9(7): 746.

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Studies on Thermokinetics (Ⅵ)——Thermokinetics for Ring-Opening Reaction of the Epichlorohydrin

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