Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (7): 737.

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The Reaction of Tetracoordinated Thiophosphoryl Compounds with Catechol

Liu Lunzu, Cao Ruzhen, Gai Baozhong, Yang Xiaohui   

  1. Institute of Elemento-Organic Chernistry, Nankai University, Tianjin
  • Received:1987-02-13 Online:1988-07-24 Published:1988-07-24

Abstract: The reaction of a series of phosphorochloridothioates with catechol in the presence of triethylamine yields a hexacoordinated phosphorus, compound Ⅱ. Phenyl thiophosphonyl chlorides reacted with catechol to produce a pentacoordina-ted phosphorus compound Ⅴ. Phenyl. pyrophosphonothioate reacts with catechol to give Ⅱ and Ⅴ. The mechanism of these reaction were discussed, too.

Key words: Phosphoranes, Phosphorates, Thiophosphates

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