Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (7): 735.

• Articles • Previous Articles     Next Articles

Study on Nitrogen-Fixation Activity of Some Unstable Cp2TiAr2 Under Mild Conditions

Liu Yiyin, Cao Xiaomin   

  1. Institute of Elemento-Organio Chemistry, Nankai University, Tianjin
  • Received:1987-01-14 Online:1988-07-24 Published:1988-07-24

Abstract: The formation of some unstable Cp2TiAr2 (1) was proved by means of determination of produced X- ions in the reaction process. The nitrogen-fixation activity of Iunder room temperature and normal pressure was studied. Some of 1 show good nitrogen-fixation catalysis. The mechanism of ammonia formation is discussed.

Key words: Diaryl titanocene, Nitrogen-fixation, Molecular nitrogen complexes

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