Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (7): 656.

• Articles • Previous Articles     Next Articles

Spin State and Axial Coordination of Dimethylamino Tailed Porphyrin Iron

Xiu Zhengkun1, Zhao Dongyuan1, Cao Xizhang1, Dong Qingchu2   

  1. Jilin University, Changchun
  • Received:1986-10-08 Online:1988-07-24 Published:1988-07-24

Abstract: Atailed porphyrin iron complex, meso-mono-CO-(4-dimethylamino butylami-do) phenyl] triphenylporphyrin iron (Ⅲ) chloride has been prepared. Experimental results by EPR, UV,Raman, Mossbauer, MCDand cyclic voltammetry methods demonstrated that high-spin iron (Ⅲ)complex shows no intermolecular coordination of the terminal group on the metal ion while five-coordinate ferrous com-plexes are formed with axial ligands.

Key words: Tailed porphyrin iron, Axial ligand

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