Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (6): 596.
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Huang Changhua, Wan Yanzhong, Lu Liangde, Liu Jingjiang
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Abstract: In this paper, compounds containing methyl trihydrogen group (acetone, methyl acetate, dimethyl sulfpxide) are investigated by FT-IR. When dilute them with,inert Solvents, the overtones of stretching model of CO and SO groupsshift to high frequency. At the same time, the C—H stretching model shifts to low frequency. It declares that CH3 interacts with O atom, but the interaction is different, from hydrogenbonding.
Key words: Tri-hydrogen group, Intermolecular force, Electrostation potential, Band shifts of IR, Heat of solution
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Huang Changhua, Wan Yanzhong, Lu Liangde, Liu Jingjiang. Investigation of Methyl Tri-Hydrogen Group[J]. Chem. J. Chinese Universities, 1988, 9(6): 596.
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http://www.cjcu.jlu.edu.cn/EN/Y1988/V9/I6/596
