Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (3): 277.

• Articles • Previous Articles     Next Articles

An Investigation on the Metal Decavanadates Coordinating with Oxine (Ⅲ)——The Synthesis, Characterization and Properties of Lithium, Potassium and Ammonium Salts

Du yaoguo1, Wang Jun1, Wang Xiaoxia1, Xiu Zhenkun1, Du Wencai2   

  1. 1. Department of Environmenial Science Jilin University, Changchun;
    2. Department of Liaoning Nornal University, Dalian
  • Received:1986-09-02 Online:1988-03-24 Published:1988-03-24

Abstract: The decayahadates of Li+,K+,NH4+ coordinating with oxine were prepared.By means of elementary analysis, molecular weight determination, GC/MS, X-rays diffraction, UVand IRspectrophotographies and thermo-analysis, the authors suggested that the structural formulae of Li+,K+,NH4+ salts are as follows:[Li(HOx)]2[Li(HOx)3]4(H2V10O28(Ox)2]·4HOx,[K(HOx)]4[K(HOx)2]2[H6V10O28(Ox)6]·2HOx,and [NH4(HOx)]4[NH4(HOx)2]2[H4V10O28(Ox)4.

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