Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (1): 9.

• Preface • Previous Articles     Next Articles

Determination of Thermodynamic Parameters of Adduct Reaction of Nic(O8H17O)2PS2]2 and (C2H5)3N by GLC Method

Yu Yunpeng, Xu Zheng, You Xiaozeng   

  1. Coordination Chemistry Institute, Nanjing University, Nanjing
  • Received:1986-08-12 Online:1988-01-24 Published:1988-01-24

Abstract: It is reported that the equilibrium constants of acid-base interaction between Ni(C8H17O)2PS2]2, and (C2H5)3Nforming 1:1 adduct were determined by GLCmethod at variable temperature. Thermodynamic parameters △Hand △Swere found. The experimental data fit the equation:lgK=-5.196(±0.328)+[1.6503(0.1144)/T]×103

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