CJCU

Chem. J. Chinese Universities ›› 1987, Vol. 8 ›› Issue (9): 851.

• Articles • Previous Articles     Next Articles

Kinetics of Methyl Methacrylate Bulk Radical Polymerization (Ⅰ)--Conformation and Concentration of Radical and Propagating Constant kp

Tian Yuan, Zeng Yingguang, Wang Guobing, Qiu Zuwen, Shen Jiacong   

  1. Department of Chemistry and Analytic and Measare Centre, Jilin University, Changchun
  • Received:1986-12-20 Online:1987-09-24 Published:1987-09-24

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Abstract: By using TM110cavity and 2mm sample tube, the ESRspectra of the propagating radical in the polymerization system of methyl methacrylatc were recorded. The concentration and conformation of radicals and the propagating constant kpwere measured.The results showed that the propagating reaction was a diffusion controlled process.

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