Chem. J. Chinese Universities ›› 1987, Vol. 8 ›› Issue (3): 273.
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Wang Jian, Liu Jingjiang, Yang Meilin, Shen Jiacong
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Abstract: The glass transition temperature Tgand T11relaxation of a series of regular star-shaped polystyrenes were measured by tortional braid analyzer(TBA) and linear dilatometer. The results show that the Tgof star-shaped polymer increases with increasing branching degree when the molecular weights of branch chains are the same, but it is lower than that of linear polystyrene of the same molecular weight. The liquid1-liquid2relaxation temperatue T11and the strength of loss peak of star polystyrene also depend on branching degree. Two-Tgtransitions in star polystyrenes with DVBmicrogel nodule were proved by comparing two type of star polystyrenes.
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Wang Jian, Liu Jingjiang, Yang Meilin, Shen Jiacong . The Glass Transition Temperature and Liquid 1-Liquid2Relaxation of Star-Shaped Polystyrene[J]. Chem. J. Chinese Universities, 1987, 8(3): 273.
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http://www.cjcu.jlu.edu.cn/EN/Y1987/V8/I3/273