Chem. J. Chinese Universities ›› 1987, Vol. 8 ›› Issue (12): 1127.

• Articles • Previous Articles     Next Articles

Molecular Motion of Star-Shaped Polystyrenes in Solution Studied by Carbon-13 NMR(Ⅰ)

Wang Han, Hua Shiying, Li Ying, Qiu Zuwen, Shen Jiacong   

  1. Chemiatry Department, Institute of Theoretical Chemistry, Jilin University, Changchun
  • Received:1986-04-18 Online:1987-12-24 Published:1987-12-24

Abstract: The carbon-13 NMR spin lattice relaxation times,line widths and Nuclear Over-hauscr Enhancements were measured for solutions of regular star-shaped polystyrenes in o-dichlorobenzene and in CDCl3. The factors, molecular weight, concentration, solvent and molecular structure,which control magnetic relaxation, were examined. The experimental data were interpreted in terms of the log-X2distribution of correlation times

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