Chem. J. Chinese Universities ›› 1987, Vol. 8 ›› Issue (12): 1064.

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Synthesis and Characterization of Ni(Ⅱ)Complex with a 14-Membered Hexaaza Macrocyclic Ligand Containing Pyridine

Liao Daizheng, Zhou Li, Wang Genglin   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1986-07-01 Online:1987-12-24 Published:1987-12-24

Abstract: A new nickel(Ⅱ) thiocyanate complex containing a 14-membered hexaaza macrocyclic ligand(L), [NiL(SCN)2]·H2O, has been prepared by template condensation of 2,6-diacetylpyridine with hydrazine. Based on IR, electronic spectra, electrical; conductance, magnetic moment, thermal and elemental analyses, this complex is proposed to have six coordinate and distorted octahedron configuration.

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