CJCU

Chem. J. Chinese Universities ›› 1987, Vol. 8 ›› Issue (1): 55.

• Articles • Previous Articles     Next Articles

Studies on Thermokinetics(Ⅴ)--Thermokinetic Method for the Second Order Reactions

Wu Xiaoping1, Qin Ziming1, Deng yu1, Cai Ruzen2   

  1. 1. Department of Chemistry. Sichuan University, Chengdu;
    2. Department of Chemistry, Ghengdu University, Chengdu
  • Received:1985-10-23 Online:1987-01-24 Published:1987-01-24

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Abstract: On the theoretical basis of thcrmokinetics proposed in previous article, the method of dimensionless paramter for second order reactions are derived in thispaper.This method has been used to study the saponification of two csters in aqueous alcohol solvents. The rate constants of these reactions calculated with this method are in agreement with the values in literatures. And therefore, the fundamental equations of thermokinctic method for second order reactions are believed to be correct.

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