CJCU

Chem. J. Chinese Universities ›› 1987, Vol. 8 ›› Issue (1): 47.

• Articles • Previous Articles     Next Articles

Studies on the Kinetics of Decomposition of Diacyl Peroxides (Ⅷ) --CIDNP Effect of the Products of Thermolysis of Octanoyl Peroxide and Hexanoyl Peroxide

Liu Youcheng, Guo Qingxiang, Liu Peiqi   

  1. Department of Chemistry, Lanzhou University, Lanzhou
  • Received:1985-11-10 Online:1987-01-24 Published:1987-01-24

PDF (PC)

Abstract: 1H ClDNP spectra recorded during the decomposition of aliphatic diacyl peroxides [(RCOO)2, R = n-C7H15(1), n-C5H11(2)] in ODCB in the presence of scavengers, such as I2, C2H5I,(CH3)2CHI, and CH2=CHCH3Br, show multiplet effect polarization for RX (X= Br, I) and disproportionate products, R-H. The reaction mechanism is discussed in terms of radical pair theory.

TrendMD: