Chem. J. Chinese Universities ›› 1986, Vol. 7 ›› Issue (3): 233.
• Articles • Previous Articles Next Articles
Zhu Shenjie, Zhang Chunhao
Received:
Online:
Published:
Abstract: Ascries of ortho-n-alkyl iodosobenzenes were synthesized from the corresponding n-alkyl iodobenzenes. Under the same conditions,it was found that with increasing in the carbon chain length of n-alkyl group, the formation of the corresponding ortho-n-alkyl iodosobenzene became more difficult and their stability decreased accordingly. Attempts for synthesizing ortho-n-alkyl iodosobenzene with carbon atoms more than five in the n-alkyl group were not successful. The structures of some ortho-n-alkyl iodosobenzenes were analyzed by ir and nmr spectra. The steric effect of the long chain n-alkyl groups in the formation of more stable polybridged structure was discussed.
TrendMD:
Zhu Shenjie, Zhang Chunhao . Study on Organo-Iodoso Compounds(Ⅰ)—The Steric Effect of Ortho-n-Alkyl Group on the Stability of Ortho-n-Alkyl Iodosobenzene[J]. Chem. J. Chinese Universities, 1986, 7(3): 233.
0 / / Recommend
Add to citation manager EndNote|Ris|BibTeX
URL: http://www.cjcu.jlu.edu.cn/EN/
http://www.cjcu.jlu.edu.cn/EN/Y1986/V7/I3/233