Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (8): 753.

• Preface • Previous Articles    

Concentration Effect on GPC Retention Volume

Zhang Hongan1, Teng Fachun1, Ge Weidong1, Zhang Min-shu2   

  1. 1. Department of Chemistry, Jilin University, Changchun;
    2. Shanghai Academia, Shanghai
  • Received:1984-01-07 Online:1985-08-24 Published:1985-08-24

Abstract: Concentration effect in the high performance GFChas been investigated. The study of the contraction of hydromechanical volume has been made htough determination of the varying values of the being clution volume with the change of concentrations.On the case of higher molecular weights and higher concentration, the curve of Vc-Cin good solvent crosses with the Vc-Ccurve in bad loivend for the samples with the same molecular weight. The point of intersection of the curves shifts to the direction of the lower concentration as the molecular weight increases.

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