CJCU

Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (8): 735.

• Preface • Previous Articles     Next Articles

The Crystal and Molecular Structure of Neodymium Chloride Isopropyl Alcohol Complex

Jin Zbongsheng1, Wang Shenglong1, Wang Fusong1, Shen Cheng2, Yang Guangdi2, Fan Yuguo2   

  1. 1. Changchun Institute of Applied Chemistry, Academic Sinica;
    2. Institute of Theoretical Chemistry of Jilin University, Changchun
  • Received:1984-03-16 Online:1985-08-24 Published:1985-08-24

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Abstract: The crystal structure of [NdCl5·(CH5CHOHCH3)]2 has been determined by X-ray diffraction method. It is triclinic and the space group is P1, with dimensions: a= 11.184(2)Å, b= 13.462(3)Å,c = 5.9794(9)Å, α = 101.37(2) °β = 93.6l(2)°,γ= 69.46(2)°. The structure was solved by patterson method. The final residual factor is R= 0.038. The feature of the crystal structure is that every two Nd ions are linked in pairs through a chlorine bridge o?two chlorine ions to form a complex molecule and every Nd ion is seven-coordinate.

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