Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (7): 577.

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Studies on the Rare Earth Complexes on Pyridine Derivatives and Their N-Oxide (Ⅰ)——The Synthesis and Properties of the Complexes of Praseodymium, Neodymium and Samarium Chlorides with 2, 2'-Bipyridine-N, N'-Dioxide

Tan Minyu, Tang Ning, Zhai Yingli, Qiu Jiabin   

  1. Departmcnt of Chemistry, Lanzhou University Lanzhou
  • Received:1983-12-28 Online:1985-07-24 Published:1985-07-24

Abstract: The solid complexes of trivalent rarc earth (Pr, Nd, Sm) chlorides with 2, 2'-bipyridine-N, N'-dioxide were prepared. The mole ratios of Ln to bipyO2 in the complexes are 1:1, 1:3, 1:4 respectively. They were characterized by elemental analysis, X-ray diffraction, infrared spectra, thermogravimetric (TG) and differential thermol analyses (DTA), as.well as molar conductance studies.

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