CJCU

Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (12): 1051.

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Study on the Complex Property of Benzo-15-Crown-5

Jin Xianglin1, Tang Youqi1, Wu Yangjie2, An Haoyun2, Hu Hongwen2   

  1. 1. Institute of Physical Chemistry, Peking University, Beijing;
    2. Chemistry Department, Zhengzhou University, Zhengzhou
  • Received:1984-07-07 Online:1985-12-24 Published:1985-12-24

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Abstract: The single crystal of complex Na (benzo-l5-crown-5)-C6H2N5O7(C6H5N3O7=Picric acid) was obtained from the acetone-ethanol solvent.The crystal belongs to monoclinic space group C2h5-P21/n.The crystallography parameters arc:a=11.134 (3)Å,b=13.541(3)Å,c=14.927(4)Å, β=93.41 (2)°, V=2246.4Å3, Z=4.The crystal structure was solved by direct methed.The result shows that the electronic density on the aromatic ether oxygen atoms conjugated with the benzen ring can be transfered through the benzen ring.

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