Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (11): 995.

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Study on the Carbonyl Substitution in Bis (μ-Alkylthio)-Hexacar-Bonyldiirons--The Synthesis and Structures of Triphenylphosphinc Fc-S Clusters(μ-RS)(μ-R'S)Fc2(CO)5Pph5)

Song Licheng, Hu Qingmei, Wang Jitao   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1984-07-21 Online:1985-11-24 Published:1985-11-24

Abstract: Fourteen new Pph3-substituted Fc-Sclusters with general formula (μ-RS)(μ-R'S)Fe2(CO)5 Pph3 have been synthesized by the reaction of unsymmetrical type of bis(μ-alkylthio)-hexacarbonyldiirons with triphenylphosphinc. Their m.p., IR, 1HNMRand C/Hanalysis have been performed. Based on the analysis of the influence of Pph3 on vco and δ-alkyl, the spacial orientation of Pph3 in these clusters has also been established.

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