CJCU

Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (10): 861.

• Articles • Previous Articles     Next Articles

Studies on Synthesis, Structure and Properties of the Cluster Complex [(C4H9)4N]2[Mo2S6O2]

Zhang Zhigui1, Li Shuqin1, Zhang Zeying2, Shao Meicheng2   

  1. 1. Department of Chemistry, Jilin University, Changchun;
    2. Institute of Physical Chemistry, Peking University, Beijing
  • Received:1984-05-03 Online:1985-10-23 Published:1985-10-23

PDF (PC)

Abstract: The crystal of the cluster complex, [(C4H9)4N]2[Mo2S6O2] was obtained by the reaction of (NH4)2MoS4, FeCl5 and (C4H9)NBr in CH3OH-CH5ONa. The crystal structure of the cluster complex was measured by X-ray. The crystal belongs to D2h15-Pcah space group. The crystal cell parameter are a=15.876(3)Å,b=17.786(6)Å,c=31.90(1)Å,V=9008.7Å3. The structure was refired by leastsquares. The value of Rwas 0.0659. The properties of IR, Raman, UV-Visible spectra and electrochemistry of the cluster complex have been investigated.

TrendMD: