Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (1): 91.
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Cao Weixiao, Shu Xiaoping, Feng Xinde
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Abstract: The photopolymerization of acrylonitrile (AN) initiated by phenothia-zine (PTZ) has been studied. The kinetic equation was determined to be Rp =Rp=K[AN]1.47[PTZ]0.41 and the activation energy of polymerization (Ea) is 7.1 Kcal/mol. Through the fluorescence spectra studies, the exciplex formation between the excited PTZand ANmonomer and an initiation mechanism involving its decomposition have been proposed.
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Cao Weixiao, Shu Xiaoping, Feng Xinde . Studies on the Charge Transfer Polymerization——The Photopolymerization of Acrylonitrile Initiated by Phenothiazine[J]. Chem. J. Chinese Universities, 1985, 6(1): 91.
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