CJCU

Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (1): 69.

• Articles • Previous Articles     Next Articles

Crystal Structure Research of Complex K4Na2{Cu[C(CH3)(OH)(PO3)2]2}·12H2O

Pan Zuohua1, Jin Xianlin1, Shao Meicheng1, Zhuang Ruifang2, Xiao Yongzhuang2   

  1. 1. Institute, of Physical Chemistry, Peking Uniecrsity, Beijing;
    2. Instilatc of Coordination Chcmistry, Nanjing Cniversity, Nanjing
  • Received:1983-07-16 Online:1985-01-24 Published:1985-01-24

PDF (PC)

Abstract: This thesis reports crystal structure of the complex, K4Na3{Cu[C-(CH)5(OH)(PO5)2]2}·12H2O. The structure was determined by Patterson method and refined by block least squares routine.The final deviation factor is:R= 0.0413.Title compound crystallizes in space group P1 with crystall-ographic parameters a=ll.951(3), b = 6.220(1), c = 11. 789(2)Å; α=113.166 (11)°β= 108.944(15)° γ = 97.563(14)°;V = 727.4Å5; Dc = 2.02g/cmÅ3 and μ(MoKa) = 16.9cm-1.The result of crystal structure, analysis shows that the copper atom in each chelate ion is coordinated by four oxygen atoms of phosphoryt groups and two oxygen atoms of hydroxyl groups.

TrendMD: