CJCU

Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (1): 49.

• Articles • Previous Articles     Next Articles

Study on the Organometallic Compounds of Transition Metals Containing Pentahaloaryl Ligands(Ⅰ)——Synthesis and Reactions of Bis(Diphenyl-Alkylphosphine)Pontachlorophenylnickel Chloride

Wang Xukun, Zhang Zhengzhi, Wei Dong   

  1. The Institute of Elementoorganie Chemistry, Nankai University, Tianjin
  • Received:1983-07-14 Online:1985-01-24 Published:1985-01-24

PDF (PC)

Abstract: The compounds of general formula (Ph2PR)2Ni(C6Cl5)Cl(R = CH3, C2H5, n-Pr, n-Bu) were synthesized. Their chemical reactions with inorganic halides and pseudohalides, as well as organolithium reagent and al-kynyl compounds were investigated. Through these reactions, a series of new organonickel compounds have been prepared and the scope of applications of some reactions has been expanded.

TrendMD: