Chem. J. Chinese Universities ›› 1984, Vol. 5 ›› Issue (6): 833.

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Synthesis of Bis(methyl-cyclopentadienyl) Titanium Dichloride and Its Derivatives

Zhou Yaokun, Feng Tiecheng   

  1. Dept, of Chmistry, Lanzhou Univ., I.anzhou
  • Received:1983-03-07 Online:1984-12-24 Published:1984-12-24

Abstract: In this paper, the bis(methyl-cyclopentadienyl) titanium dichloride is prepared by means of reaction of methyl-cyclopentadienyl lithium with titanium tetrachloride. Some new dimethylcyclopentadienyl compounds of titanium such as (MeCp)2Ti (OR)2 and (MeCp)2Ti (OR') Cl (R = C6H3Me2-2,4, C6H4NO2-3, C6H4NO2-4; R' = C6H3Me2-3,5) have also been synthesized. Their IR and 1HNMR spectra are given.

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