Chem. J. Chinese Universities ›› 1984, Vol. 5 ›› Issue (4): 477.

• Articles • Previous Articles     Next Articles

Investigation on Oscillopolarographic Titrations (ⅩⅪ)——Oscillopolarographic Chelometric Titrations Using the Incisions Produced by Addition of Chelating Reagents to Mercury Electrodes

Tao Shuguang, Gao Hong(H. Kao)   

  1. Department of Chemistry, Nanjing University, Nanjing
  • Received:1983-06-27 Online:1984-10-24 Published:1984-10-24

Abstract: Oscillopolarographic chelometric titrations usually use the disappearance of the incisions of the electrode active ions to be titrated to indicate end-points of titrations. When the titrated ion is not electro-active, an indicator is usually required. It was found that EDTAand its related compounds such as DTPAand CyDTAcould complex with Hg3+ ions produced on mercury electrode and thus yield incisions of Hg2+ complexes which could be used to indicate the end-point of the chelometric titra-tion. Aseries of such titrations without indicators have been developed. It was shown that direct titrations of Ca3+ , Mg3+ , Sr3+ , Ni3+ , Mn2+, Co3+ and lanthanide ions could be carried out with DTPA and CyDTA and even EDTA.

TrendMD: