Chem. J. Chinese Universities ›› 1982, Vol. 3 ›› Issue (4): 495.
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Liu Yiyin, Chen Shoushan
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Abstract: Acidolysis reactions of bis-(cyclopentadienyl)-di-(aryloxy)-titanium were studied. It was proved that acidolysis reactions go step by step. According to the reaction conditions, the second-step acidolysis product, bis-(cyclopentadienyl)-titanium dihalides, and the first-step acidolysis product, bis-(cyclopentadienyl)-(aryloxy)-titanium halides, were obtained. Reaction conditions were discussed.Through above-mentioned reactions, a series of new bis-(cyclopentadi nyl)-(aryloxy)-titanium halides have been synthesized with good yields.Starting from bis-(cyclopentadienyl)-(aryloxy)-titanium halides, a few new derivatives with formulae Cp2Ti(OAr)Ar and Cp2Ti(OAr)(OAr') have prepared.
TrendMD:
Liu Yiyin, Chen Shoushan . ACIDOLYSIS REACTIONS OF BIS(CYCLOPEN-TADIENYL)-DI-(ARYLOXY)-TITANIUM[J]. Chem. J. Chinese Universities, 1982, 3(4): 495.
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