Chem. J. Chinese Universities ›› 1981, Vol. 2 ›› Issue (1): 117.

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INVESTIGATIONS ON OSCILLOPOLAROG RAPHIC TITRATION——V——TITRATION OF Ni BY DIMETHYLGLYOXIME

Weng Yunrong, Chern Tzunrong, Kao Hung   

  1. Department of Chemistry, Nanjing University, Nanjing
  • Received:1980-07-04 Online:1981-01-24 Published:1981-01-24

Abstract: In NH4OH-NH4Cl buffer solution, Ni can be directly titrated by standard alcoholic solution of dimethylglyoxime, using the appearanceof the incision on (dE)/(dt) - Ecurve of dimethylglyoxime to indicate the endpoint of titration.Fe(III), Al(III), Mn(IV), Ti(IV) and Pb(II) which form precipitates in the medium do not interfere.This is an example to show that tedious gravimetric technique can be advantageously replaced by a simpler volumetric technique of oscillopolarographic titration.

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