Chem. J. Chinese Universities ›› 1980, Vol. 1 ›› Issue (1): 66.
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Yang Shih-hsien, Chen Ju-yu, Liu Zhun, Chen Jinlong, Wang Likun, Shi Guozhu
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Abstract: Five new 7-oxo-alkanoic acids,R-CO-(CH2)6-COOH (Where R=CH3-(CH2)13,CH3(CH2)15,CH3(CH2)17,CH3(CH2)20and CH3(CH2)32),have been prepared by the reaction of carboxylic chlorides with 1-morpholino -1-cyclohexene.The acids thus formed were reduced twice by first Huang-Minion modification of the Wolff-Kishner method and then lithium aluminum hydride,giving the corresponding higher primary alkanols.We studied the necessary conditions of the reaction of long chain acyl chlorides with 1-morpholino-l-cyclohexene in the presence of triethyl amine and successfully prepared the 7-oxo-alkanoic acids.
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Yang Shih-hsien, Chen Ju-yu, Liu Zhun, Chen Jinlong, Wang Likun, Shi Guozhu. SYNTHESIS OF HIGHER PRIMARY ALKANOLS[J]. Chem. J. Chinese Universities, 1980, 1(1): 66.
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http://www.cjcu.jlu.edu.cn/EN/Y1980/V1/I1/66
