Chem. J. Chinese Universities ›› 2021, Vol. 42 ›› Issue (5): 1530.doi: 10.7503/cjcu20200503
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LI Shiheng, WANG Chao, LU Zhenda()
Received:
2020-07-31
Online:
2021-05-10
Published:
2020-10-20
Contact:
LU Zhenda
E-mail:luzhenda@nju.edu.cn
Supported by:
CLC Number:
TrendMD:
LI Shiheng, WANG Chao, LU Zhenda. Challenges and Recent Progress of Prelithiation for Si-Based Anodes in Lithium-ion Batteries[J]. Chem. J. Chinese Universities, 2021, 42(5): 1530.
Method | Introduction | Advantages and disadvantages |
---|---|---|
Stable lithium micron particles(SLMP) | SLMP are directly coated on the silicon electrode or mixed into the silicon anode slurry | Simple operation, controllable degree of prelithiation, but expensive and holes generated in the electrode after cycling |
Lithium metal additives | Lithium foil is added directly to the silicon electrode | Low cost and simple operation |
Self?discharge lithiation | Tightly contacting electrode with lithium metal in the presence of electrolyte | No voltage is needed, but it is difficult to precisely control the degree of prelithiation |
Electrochemical lithiation | Needing temporary battery construction and electric shorting the electrode and lithium metal | Precisely controlling the degree of lithium, but more complicated |
Thermal lithiation | Prelithiating silicon with molten lithium | The degree of prelithiation can be controlled, but the resulting lithium silicon alloy has poor compatibility with conventional solvents |
Organic?lithium prelithiation | Prelithiating silicon with organic?lithium in solvent | Difficult to control the amount of organic?lithium and requiring an additional solvent cleaning process |
Method | Introduction | Advantages and disadvantages |
---|---|---|
Stable lithium micron particles(SLMP) | SLMP are directly coated on the silicon electrode or mixed into the silicon anode slurry | Simple operation, controllable degree of prelithiation, but expensive and holes generated in the electrode after cycling |
Lithium metal additives | Lithium foil is added directly to the silicon electrode | Low cost and simple operation |
Self?discharge lithiation | Tightly contacting electrode with lithium metal in the presence of electrolyte | No voltage is needed, but it is difficult to precisely control the degree of prelithiation |
Electrochemical lithiation | Needing temporary battery construction and electric shorting the electrode and lithium metal | Precisely controlling the degree of lithium, but more complicated |
Thermal lithiation | Prelithiating silicon with molten lithium | The degree of prelithiation can be controlled, but the resulting lithium silicon alloy has poor compatibility with conventional solvents |
Organic?lithium prelithiation | Prelithiating silicon with organic?lithium in solvent | Difficult to control the amount of organic?lithium and requiring an additional solvent cleaning process |
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