Fabrication of Cu3(BTC)2 Mixed Matrix Membrane and Its Application in Continuous Flow Process †

doi:10.7503/cjcu20190250

Abstract

Abstract:

A Cu₃(BTC)₂@PS mixed matrix membrane(MMM) with 60%(mass fraction) MOF loading was fabricated via solvent evaporation method. The catalyst was characterized by means of SEM, XRD, FTIR and TGA. The results showed that Cu₃(BTC)₂ MOF uniformly distributed on the MMM and the MMM possessed a good thermal stability. The copper of the Cu-BTC MMM served as the active sites for the flow reaction system. The as-synthesized membranes possess high surface area and excellent hydrophilicity. Cu₃(BTC)₂ MMM was evaluated as a catalyst for the aldehyde acetalization with ethanol. 99% conversion of benzaldehyde and 99% selectivity of benzaldehyde diethyl acetal was obtained, using Cu₃(BTC)₂MMM heterogeneous catalyst for 24 h. It has an excellent practicality to develop this simple mixed matrix membrane for industrial application.

Key words: Metal organic framework(MOF), Cu₃(BTC)₂, Mixed matrix membrane, Acetalization

CLC Number:

O643

TrendMD:

HOU Junying, HAO Jianjun, WANG Yaya, LIU Jingchun. Fabrication of Cu₃(BTC)₂ Mixed Matrix Membrane and Its Application in Continuous Flow Process ^†[J]. Chem. J. Chinese Universities, 2019, 40(9): 1926.

Figures/Tables 8

References 40

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Sample	S_BET/ (m²·g^-1)	V_p/ (cm³·g^-1)	D_p/nm
Cu₃(BTC	1447	0.56	1.55
Cu₃(BTC)₂ MMM	79	0.12	2.35

Sample	S_BET/ (m²·g^-1)	V_p/ (cm³·g^-1)	D_p/nm
Cu₃(BTC	1447	0.56	1.55
Cu₃(BTC)₂ MMM	79	0.12	2.35

Fabrication of Cu₃(BTC)₂ Mixed Matrix Membrane and Its Application in Continuous Flow Process ^†

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Entry	Catalyst	Substrate	Conversion^b(%)	Selectivity^b(%)
1	PS	Benzaldehyde
2	Cu₃(BTC)₂	Benzaldehyde	99	99
3	Cu₃(BTC)₂ MMM	Benzaldehyde	99	99
4	Cu₃(BTC)₂ MMM	p-Methoxybenzaldehyde	86	99
5	Cu₃(BTC)₂ MMM	4-Fluorobenzaldehyde	99	99
6	Cu₃(BTC)₂ MMM	Phenylacetaldehyde	99	99
7	Cu₃(BTC)₂ MMM	Furfuraldehyde	85	99
8	Cu₃(BTC)₂ MMM	1-Octaldehyde	93	99

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