Preparation and Thermochromic Property of Fe3+-doped Sm3Ga5O12†

doi:10.7503/cjcu20180606

Abstract

Abstract:

The reversible thermochromic materials, Fe³⁺-doped Sm₃Ga₅O₁₂, was prepared via high temperature solid state reaction method, and their structure and properties were characterized by X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FTIR), Raman spectroscopy, scanning electron microscopy(SEM), X-ray photoelectron spectroscopy(XPS) and UV-Vis spectroscopy. With the increase of Fe³⁺ doping, the samples’ color gradually changed from bright yellow-green to dark green at room temperature, and when the temperature was increased from room temperature to 500 ℃, the color of the samples gradually turned to orange and brown. The yellow-green color of the sample at room temperature is due to its absorption in the violet region and orange-red region, and continuous red shift of absorption edge is accompanied by changes in color with temperature increasing.

Key words: Fe³⁺-doped Sm₃Ga₅O₁₂, Color tuning, Thermochromism

CLC Number:

O611

TrendMD:

LIU Huanhuan,YUAN Long,LIU Jinghai,HOU Changmin,FENG Shouhua. Preparation and Thermochromic Property of Fe³⁺-doped Sm₃Ga₅ $O 12 †$ [J]. Chem. J. Chinese Universities, 2019, 40(4): 652.

Figures/Tables 10

Fig.1 Photographs(insets) and CIE-Lab parameters at different temperatures of Sm3Ga5-xFexO12[x=1(A), 2(B), 3(C), 4(D)]

Fig.2 Rietveld refinement pattern for XRD patterns of Sm3Ga5-xFexO12[x=1(A), 2(B), 3(C), 4(D)]

Table 1 Refinement results of Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Sample	Space group	Lattice parameter/nm	Volume/nm³	R_wp(%)	R_p(%)
Sm₃Ga₄FeO₁₂	Ia $3 ˉ$ d(230)	1.24672(4)	1.93779	11.13	6.74
Sm₃Ga₃Fe₂O₁₂	Ia $3 ˉ$ d(230)	1.24785(1)	1.94306	10.74	7.15
Sm₃Ga₂Fe₃O₁₂	Ia $3 ˉ$ d(230)	1.24977(0)	1.95205	9.82	6.66
Sm₃GaFe₄O₁₂	Ia $3 ˉ$ d(230)	1.25162(3)	1.96073	10.15	6.68

Table 1 Refinement results of Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Sample	Space group	Lattice parameter/nm	Volume/nm³	R_wp(%)	R_p(%)
Sm₃Ga₄FeO₁₂	Ia $3 ˉ$ d(230)	1.24672(4)	1.93779	11.13	6.74
Sm₃Ga₃Fe₂O₁₂	Ia $3 ˉ$ d(230)	1.24785(1)	1.94306	10.74	7.15
Sm₃Ga₂Fe₃O₁₂	Ia $3 ˉ$ d(230)	1.24977(0)	1.95205	9.82	6.66
Sm₃GaFe₄O₁₂	Ia $3 ˉ$ d(230)	1.25162(3)	1.96073	10.15	6.68

Fig.3 FTIR spectra in the range of 400—4000 cm-1 for Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Fig.4 Raman spectra in the range of 100—800 cm-1 for Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Fig.5 SEM images of Sm3Ga5-xFexO12[x=1(A), 2(B), 3(C), 4(D)]

Fig.6 XPS of Fe2P spectra for Sm3Ga5-xFexO12[x=1(A), 2(B), 3(C), 4(D)]

Fig.7 UV-Vis spectra(Kubelka-Munk transformed) of Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Fig.8 Temperature dependent UV-Vis spectra of Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Table 2 Photographs of the reversible thermochromic cycle experiment

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Preparation and Thermochromic Property of Fe³⁺-doped Sm₃Ga₅ $O 12 †$

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