Chem. J. Chinese Universities ›› 2019, Vol. 40 ›› Issue (2): 350.doi: 10.7503/cjcu20180241
• Physical Chemistry • Previous Articles Next Articles
ZHU Hongtai2, SONG Liyun1,2, HE Hong1,2,*(), YIN Mengqi2, CHENG Jie2, SUN Yanming2, LI Shining2, QIU Wenge1,2
Received:
2018-03-29
Online:
2019-02-10
Published:
2018-09-10
Contact:
HE Hong
E-mail:hehong@bjut.edu.cn
Supported by:
CLC Number:
TrendMD:
ZHU Hongtai,SONG Liyun,HE Hong,YIN Mengqi,CHENG Jie,SUN Yanming,LI Shining,QIU Wenge. Sulfur Tolerance of the CeTiOx Catalysts for Selective Catalytic Reduction of NO with NH3†[J]. Chem. J. Chinese Universities, 2019, 40(2): 350.
Fig.1 NH3-SCR activity(A) and N2 selectivity(B) over the catalystsReaction conditions: 0.1%NO+0.1%NH3+6%O2+0.0175%SO2+6%H2O, He balance, GHSV: 3×104 h-1. a. CeTiOx-A; b. CeTiOx-B; c. 40CeTiOx-A; d. 40CeTiOx-B; e. 60CeTiOx-A; f. 60CeTiOx-B.
Fig.2 NH3-SCR activity over CeTiOx-A(a) and CeTiOx-B(b) in the presence of SO2/H2O at 300 ℃Reaction condition: 0.1%NO+0.1%NH3+6%O2+0.0175%SO2+6%H2O, N2 balance, GHSV: 3×104 h-1.
Sample | Component content(mass fraction, %) | BET surface area/(m2·g-1) | Pore volume/(cm3·g-1) | ||
---|---|---|---|---|---|
TiO2 | CeO2 | SO3 | |||
CeTiOx-A | 67.5 | 31.8 | 0.41 | 112 | 0.34 |
CeTiOx-B | 64.6 | 34.7 | 0.36 | 105 | 0.30 |
40CeTiOx-A | 61.5 | 31.8 | 6.32 | 66 | 0.26 |
40CeTiOx-B | 61.2 | 33.9 | 4.51 | 52 | 0.19 |
60CeTiOx-A | 62.1 | 31.7 | 5.83 | 60 | 0.25 |
60CeTiOx-B | 60.4 | 33.2 | 6.06 | 52 | 0.19 |
Table 1 Component content, BET surface area and pore volume of the catalysts
Sample | Component content(mass fraction, %) | BET surface area/(m2·g-1) | Pore volume/(cm3·g-1) | ||
---|---|---|---|---|---|
TiO2 | CeO2 | SO3 | |||
CeTiOx-A | 67.5 | 31.8 | 0.41 | 112 | 0.34 |
CeTiOx-B | 64.6 | 34.7 | 0.36 | 105 | 0.30 |
40CeTiOx-A | 61.5 | 31.8 | 6.32 | 66 | 0.26 |
40CeTiOx-B | 61.2 | 33.9 | 4.51 | 52 | 0.19 |
60CeTiOx-A | 62.1 | 31.7 | 5.83 | 60 | 0.25 |
60CeTiOx-B | 60.4 | 33.2 | 6.06 | 52 | 0.19 |
Sample | H2 consumption/(μmol·g-1) | Sample | H2 consumption/(μmol·g-1) | ||||
---|---|---|---|---|---|---|---|
Peak 1 | Peak 2 | Total | Peak 1 | Peak 2 | Total | ||
CeTiOx-A | 36 | - | 36 | 40CeTiOx-B | 270 | 163 | 432 |
CeTiOx-B | 30 | - | 30 | 60CeTiOx-A | 117 | 69 | 186 |
40CeTiOx-A | 106 | 53 | 159 | 60CeTiOx-B | 319 | 187 | 506 |
Table 2 H2 consumption of the catalysts
Sample | H2 consumption/(μmol·g-1) | Sample | H2 consumption/(μmol·g-1) | ||||
---|---|---|---|---|---|---|---|
Peak 1 | Peak 2 | Total | Peak 1 | Peak 2 | Total | ||
CeTiOx-A | 36 | - | 36 | 40CeTiOx-B | 270 | 163 | 432 |
CeTiOx-B | 30 | - | 30 | 60CeTiOx-A | 117 | 69 | 186 |
40CeTiOx-A | 106 | 53 | 159 | 60CeTiOx-B | 319 | 187 | 506 |
Fig.5 XPS results of Ti2p(A), S2p(B), Ce3d(C) and O1s(D) of the catalystsa. CeTiOx-A; b. CeTiOx-B; c. 40CeTiOx-A; d. 40CeTiOx-B; e. 60CeTiOx-A; f. 60CeTiOx-B.
Sample | Surface atomic concentration(%) | Surface atomic ratio(%) | ||||
---|---|---|---|---|---|---|
Ce | Ti | O | S | Ce3+/(Ce3++Ce4+) | Oα/(Oα+Oβ) | |
CeTiOx-A | 2.6 | 32.6 | 63.6 | 1.2 | 22.8 | 35.9 |
CeTiOx-B | 1.6 | 34.2 | 63.2 | 1.0 | 19.8 | 35.1 |
40CeTiOx-A | 1.4 | 29.1 | 65.3 | 4.2 | 45.2 | 55.9 |
40CeTiOx-B | 1.3 | 31.4 | 64.3 | 3.0 | 42.0 | 52.1 |
60CeTiOx-A | 1.4 | 29.9 | 64.9 | 3.9 | 36.1 | 53.9 |
60CeTiOx-B | 1.0 | 30.8 | 64.5 | 3.7 | 35.1 | 37.5 |
Table 3 XPS results of the catalysts
Sample | Surface atomic concentration(%) | Surface atomic ratio(%) | ||||
---|---|---|---|---|---|---|
Ce | Ti | O | S | Ce3+/(Ce3++Ce4+) | Oα/(Oα+Oβ) | |
CeTiOx-A | 2.6 | 32.6 | 63.6 | 1.2 | 22.8 | 35.9 |
CeTiOx-B | 1.6 | 34.2 | 63.2 | 1.0 | 19.8 | 35.1 |
40CeTiOx-A | 1.4 | 29.1 | 65.3 | 4.2 | 45.2 | 55.9 |
40CeTiOx-B | 1.3 | 31.4 | 64.3 | 3.0 | 42.0 | 52.1 |
60CeTiOx-A | 1.4 | 29.9 | 64.9 | 3.9 | 36.1 | 53.9 |
60CeTiOx-B | 1.0 | 30.8 | 64.5 | 3.7 | 35.1 | 37.5 |
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