Chem. J. Chinese Universities ›› 2015, Vol. 36 ›› Issue (3): 523.doi: 10.7503/cjcu20140895
• Physical Chemistry • Previous Articles Next Articles
CHAO Jingdi2, HE Hong1,2,*(), SONG Liyun2, FANG Yujiao2, LIANG Quanming1, ZHANG Guizhen1,2, QIU Wenge1,2, ZHANG Ran2
Received:
2014-10-09
Online:
2015-03-10
Published:
2015-01-30
Contact:
HE Hong
E-mail:hehong@bjut.edu.cn
Supported by:
CLC Number:
TrendMD:
CHAO Jingdi, HE Hong, SONG Liyun, FANG Yujiao, LIANG Quanming, ZHANG Guizhen, QIU Wenge, ZHANG Ran. Promotional Effect of Pr-Doping on the NH3-SCR Activity over the V2O5-MoO3/TiO2 Catalyst†[J]. Chem. J. Chinese Universities, 2015, 36(3): 523.
Sample | Content of Pr(%) | SBET/(m2·g-1) | Pore volume/(cm3·g-1) | Crystallite size/nm |
---|---|---|---|---|
TiO2 | 34.8 | 0.06 | 29.8 | |
2Pr-TiO2 | 2 | 76.0 | 0.12 | 11.6 |
4Pr-TiO2 | 4 | 123.2 | 0.19 | 12.0 |
8Pr-TiO2 | 8 | 101.5 | 0.16 | 11.7 |
3V6MoTi | 15.7 | 0.03 | 33.6 | |
3V6Mo2PrTi | 2 | 64.5 | 0.10 | 12.2 |
3V6Mo4PrTi | 4 | 85.0 | 0.14 | 12.7 |
3V6Mo8PrTi | 8 | 87.6 | 0.16 | 12.6 |
Table 1 SBET, pore volume and average crystallite size of the Pr6O11-TiO2 supports and V2O5-MoO3/Pr6O11-TiO2 catalysts
Sample | Content of Pr(%) | SBET/(m2·g-1) | Pore volume/(cm3·g-1) | Crystallite size/nm |
---|---|---|---|---|
TiO2 | 34.8 | 0.06 | 29.8 | |
2Pr-TiO2 | 2 | 76.0 | 0.12 | 11.6 |
4Pr-TiO2 | 4 | 123.2 | 0.19 | 12.0 |
8Pr-TiO2 | 8 | 101.5 | 0.16 | 11.7 |
3V6MoTi | 15.7 | 0.03 | 33.6 | |
3V6Mo2PrTi | 2 | 64.5 | 0.10 | 12.2 |
3V6Mo4PrTi | 4 | 85.0 | 0.14 | 12.7 |
3V6Mo8PrTi | 8 | 87.6 | 0.16 | 12.6 |
Fig.2 Conversion of NOx(A), selectivity of N2 and production of N2O(B) over the V2O5-MoO3/Pr6O11-TiO2 catalysts Test condition: 760 mg/m3 NH3, 1340 mg/m3 NO, 8%O2, He balance, space velocity: 3×104 h-1.
Sample | A(V4+)/A(V2p) | A(Oα)/A(O1s) |
---|---|---|
3V6MoTi | 0.12 | 0.15 |
3V6Mo4PrTi | 0.11 | 0.20 |
Table 2 XPS data of the catalysts*
Sample | A(V4+)/A(V2p) | A(Oα)/A(O1s) |
---|---|---|
3V6MoTi | 0.12 | 0.15 |
3V6Mo4PrTi | 0.11 | 0.20 |
Fig.5 In situ DRIFTS spectra of NH3 adsorption over the 3V6MoTi(A) and 3V6Mo4PrTi(B) catalysts Temperature/℃: a. 40; b. 100; c. 150; d. 200; e. 250; f. 300.
Fig.7 Effects of SO2 and H2O on the NOx conversion over 3V6MoTi(a) and 3V6Mo4PrTi(b) catalysts at 260 ℃ Reaction condition: NH3(760 mg/m3), NO(1340 mg/m3), O2(8%), SO2(1430 mg/m3), H2O(5%), N2 balance, space velocity: 3×104 h-1.
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