Chem. J. Chinese Universities ›› 2018, Vol. 39 ›› Issue (2): 284.doi: 10.7503/cjcu20170480
• Physical Chemistry • Previous Articles Next Articles
GAO Jun, HU Hui*(), LIU Xueyan
Received:
2017-07-19
Online:
2018-02-10
Published:
2018-01-11
Contact:
HU Hui
E-mail:huhhust@163.com
CLC Number:
TrendMD:
GAO Jun, HU Hui, LIU Xueyan. Preparation and Evaluation of Modified Cyanobacteria-derived Activated Carbon for CO2 Adsorption†[J]. Chem. J. Chinese Universities, 2018, 39(2): 284.
Proximate analysisa | Ultimate analysis | ||
---|---|---|---|
Component | Mass fraction(%) | Element | Mass fraction(%) |
Moisture | 15.03 | C | 43.28 |
Volatile | 68.04 | H | 6.36 |
Ash | 5.97 | Ob | 35.81 |
Fixed carbon | 10.96 | N | 7.70 |
S | 0.88 |
Table 1 Proximate and ultimate analysis of cyanobacteria
Proximate analysisa | Ultimate analysis | ||
---|---|---|---|
Component | Mass fraction(%) | Element | Mass fraction(%) |
Moisture | 15.03 | C | 43.28 |
Volatile | 68.04 | H | 6.36 |
Ash | 5.97 | Ob | 35.81 |
Fixed carbon | 10.96 | N | 7.70 |
S | 0.88 |
Sample | SBET/(m2·g-1) | Vtotal/(cm3·g-1) | Vmicro(cm3·g-1) | |
---|---|---|---|---|
AC | 10.7 | 0.011 | 4.02 | |
ACK-1-6 | 705 | 0.429 | 0.344 | 4.62 |
ACK-1-7 | 932 | 0.514 | 0.425 | 2.87 |
ACK-1-8 | 1247 | 0.646 | 0.491 | 2.65 |
ACK-2-6 | 1006 | 0.578 | 0.505 | 2.30 |
ACK-2-7 | 1694 | 0.887 | 0.700 | 2.10 |
ACK-2-8 | 1951 | 1.092 | 0.756 | 2.27 |
ACK-3-6 | 970 | 0.545 | 0.454 | 2.23 |
ACK-3-7 | 1111 | 0.592 | 0.487 | 2.13 |
ACK-3-8 | 1854 | 0.992 | 0.724 | 2.26 |
Table 2 Structural parameters for AC and ACK-X-Y samples
Sample | SBET/(m2·g-1) | Vtotal/(cm3·g-1) | Vmicro(cm3·g-1) | |
---|---|---|---|---|
AC | 10.7 | 0.011 | 4.02 | |
ACK-1-6 | 705 | 0.429 | 0.344 | 4.62 |
ACK-1-7 | 932 | 0.514 | 0.425 | 2.87 |
ACK-1-8 | 1247 | 0.646 | 0.491 | 2.65 |
ACK-2-6 | 1006 | 0.578 | 0.505 | 2.30 |
ACK-2-7 | 1694 | 0.887 | 0.700 | 2.10 |
ACK-2-8 | 1951 | 1.092 | 0.756 | 2.27 |
ACK-3-6 | 970 | 0.545 | 0.454 | 2.23 |
ACK-3-7 | 1111 | 0.592 | 0.487 | 2.13 |
ACK-3-8 | 1854 | 0.992 | 0.724 | 2.26 |
Sample | SBET/(m2·g-1) | Vtotal/(cm3·g-1) | Vmicro/(cm3·g-1) | CO2 uptake at 1.01×105 Pa/(mmol·g-1) | |
---|---|---|---|---|---|
ACK-2-8 | 1951 | 1.092 | 0.756 | 2.27 | 3.85 |
ACK-2-8-1 | 1846 | 1.023 | 0.735 | 2.22 | 4.41 |
ACK-2-8-2 | 1901 | 1.026 | 0.726 | 2.26 | 3.97 |
ACK-2-8-3 | 2125 | 1.238 | 0.834 | 2.33 | 4.63 |
Table 3 Structural parameters and CO2 adsorption capacity(25 ℃) for ACK-2-8 and ACK-2-8-X samples
Sample | SBET/(m2·g-1) | Vtotal/(cm3·g-1) | Vmicro/(cm3·g-1) | CO2 uptake at 1.01×105 Pa/(mmol·g-1) | |
---|---|---|---|---|---|
ACK-2-8 | 1951 | 1.092 | 0.756 | 2.27 | 3.85 |
ACK-2-8-1 | 1846 | 1.023 | 0.735 | 2.22 | 4.41 |
ACK-2-8-2 | 1901 | 1.026 | 0.726 | 2.26 | 3.97 |
ACK-2-8-3 | 2125 | 1.238 | 0.834 | 2.33 | 4.63 |
Sample | SBET/(m2·g-1) | CO2 uptake at 1.01×105 Pa/(mmol·g-1) | Ref. |
---|---|---|---|
ACK-2-8 | 1951 | 3.85 | This work |
ACK-2-8-1 | 1846 | 4.41 | This work |
ACK-2-8-2 | 1901 | 3.97 | This work |
ACK-2-8-3 | 2125 | 4.63 | This work |
N-doped porous carbons NC-1-600 | 807 | 4.07 | [ |
NC-2-600 | 986 | 4.61 | [ |
N-doped porous carbons(coconut shell) NC-650-3 | 1535 | 4.8 | [ |
NC-700-3 | 1596 | 4.7 | [ |
NC-700-4 | 1937 | 4.4 | [ |
Porous carbon(petroleum coke) K4-700 | 1745 | 3.45 | [ |
Porous carbon(rice husk char) PC1-710 | 1041 | 4.16 | [ |
PC3-780 | 2695 | 3.71 | [ |
Activated carbon(bamboo) bamboo-3-873 | 1846 | 4.5 | [ |
N-doped active carbon(chitosan) AC800 | 728 | 4.17 | [ |
Activated carbons(pine cone shell) PAC-650/2 | 3135 | 4.73 | [ |
Activated carbon(petroleum coke) UC-650-2 | 1394 | 4.4 | [ |
Porous carbon(popcorn) PC-0.5K | 867 | 4.6 | [ |
Porous carbon(waste polyurethane foam) PUF-400-KOH-1-700 | 1516 | 4.33 | [ |
Table 4 Comparison of CO2 adsorption and SBET on various materials
Sample | SBET/(m2·g-1) | CO2 uptake at 1.01×105 Pa/(mmol·g-1) | Ref. |
---|---|---|---|
ACK-2-8 | 1951 | 3.85 | This work |
ACK-2-8-1 | 1846 | 4.41 | This work |
ACK-2-8-2 | 1901 | 3.97 | This work |
ACK-2-8-3 | 2125 | 4.63 | This work |
N-doped porous carbons NC-1-600 | 807 | 4.07 | [ |
NC-2-600 | 986 | 4.61 | [ |
N-doped porous carbons(coconut shell) NC-650-3 | 1535 | 4.8 | [ |
NC-700-3 | 1596 | 4.7 | [ |
NC-700-4 | 1937 | 4.4 | [ |
Porous carbon(petroleum coke) K4-700 | 1745 | 3.45 | [ |
Porous carbon(rice husk char) PC1-710 | 1041 | 4.16 | [ |
PC3-780 | 2695 | 3.71 | [ |
Activated carbon(bamboo) bamboo-3-873 | 1846 | 4.5 | [ |
N-doped active carbon(chitosan) AC800 | 728 | 4.17 | [ |
Activated carbons(pine cone shell) PAC-650/2 | 3135 | 4.73 | [ |
Activated carbon(petroleum coke) UC-650-2 | 1394 | 4.4 | [ |
Porous carbon(popcorn) PC-0.5K | 867 | 4.6 | [ |
Porous carbon(waste polyurethane foam) PUF-400-KOH-1-700 | 1516 | 4.33 | [ |
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