Synthesis and Properties of High-oil Absorption Resin Modified with Organic Bentonite†

doi:10.7503/cjcu20140817

Chem. J. Chinese Universities ›› 2014, Vol. 35 ›› Issue (12): 2510.doi: 10.7503/cjcu20140817

• Articles: Inorganic Chemistry • Previous Articles Next Articles

Synthesis and Properties of High-oil Absorption Resin Modified with Organic Bentonite^†

CHEN Xiaolei^1,², DENG Lichuan¹, WANG Xiaofeng³, GUAN Shuang^1,^2,^*()

1. School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China
2. Advanced Institute of Materials Science,Changchun University of Technology, Changchun 130012, China
3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry,Jilin University, Changchun 130012, China

Received:2014-09-09 Online:2014-12-10 Published:2014-11-29
Contact: GUAN Shuang E-mail:guanshuang@mail.ccut.edu.cn
Supported by:
† Supported by the Science Foundation for Youths of Science and Technology Department of Jilin Province, China(No.201201115) and the 12th Five-Year Plan for Science & Technology Research of Department of Education of Jilin Province, China(No.2014479)

Abstract

Abstract:

Cetyl-trimethyl ammonium bromide(CTAB) was used as a surface modifier to prepare hydrophobic organic bentonite. Then hexadecyl methacrylate was used to synthesize oil-absorptive resin with organic bentonite. X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FTIR) and scanning electron microscopy(SEM) were used to characterize the samples. The results show that the layer spacing of bentonite increases from 1.12 nm to 1.87 nm. When the concentrations(mass ratio to the monomer, hexadecyl methacrylate) of divinylbenzene(DVB), benzoyl peroxide(BPO), polyvinyl alcohol(PVA) and organic bentonite were 1.4%, 1.2%, 0.8% and 0.2%, respectively, the oil absorbency of the resin could reach 16.3 g/g.

Key words: High-oil adsorption resin, Organic bentonite, Oil absorption

CLC Number:

TrendMD:

CHEN Xiaolei, DENG Lichuan, WANG Xiaofeng, GUAN Shuang. Synthesis and Properties of High-oil Absorption Resin Modified with Organic Bentonite^†[J]. Chem. J. Chinese Universities, 2014, 35(12): 2510.

Figures/Tables 10

Fig.1 XRD patterns of inorganic bentonite(a) and organic bentonite(b)

Fig.2 FTIR spectra of inorganic bentonite(a) and organic bentonite(b)

Scheme 1 Synthetic routes of the resin

Fig.3 FTIR spectrum of the resin

Fig.4 SEM images of the resins without(A) and with(B) organic bentonite Insets are the surface images of the resins.

Fig.5 Effect of DVB concentration on oil absorbency of the resin

Fig.6 Effect of BPO concentration on oil absorbency of the resin

Fig.7 Effect of PVA concentration on oil absorbency of the resin

Fig.8 Effect of organic bentonite concentration on oil absorbency of the resin

Scheme 2 Interactions among DVB, BPO, PVA and organic bentonite particles

References 23

[1]	Zhang Y. L., Fang T., Yu X. J., Chem. Res. Chinese Universities, 2013, 29(1), 144—149
[2]	Gao J. Z., Li X. F., Lu Q. F., Polym. Bull., 2012, 68(1), 37—51
[3]	Zhang S. Y., Zhang Y. L., Su X. S., Zhang Y., Chem. Res. Chinese Universities, 2013, 29(1), 37—41
[4]	Zhou X. M., Chuai C. Z., J. Appl. Polym. Sci., 2010, 115, 3321—3325
[5]	Gui X. C., Li H. B., Wang K. L., Acta Mater., 2011, 59, 4798—4804
[6]	Gui X. C., Wei J. Q., Wang K. L., Adv. Mater., 2010, 22, 617—621
[7]	Zhou X. M., Chuai C. Z., Polym.Eng. Sci., 2012, 53(3), 540—545
[8]	Zadaka-Amir D., Bleiman N., Mishael Y. G., Micropor. Mesopor. Mater., 2013, 169, 153—159
[9]	Wu K., Chu X. Z., Zhou S. Y., Zhao Y. J., Journal of Chemical Engineering of Chinese Universities,2013, 27(1), 76—83
	(吴奎, 褚效中, 周守勇, 赵宜江. 高校化学工程学报,2013, 27(1), 76—83)
[10]	Shogren R. L., Doane W. M., Poly. Degrad. Stab., 2003, 79(3), 405—411
[11]	Partha K., Indra M. M., Separation and Purification Technology, 2013, 118, 519—529
[12]	Lu J. M., Guo Y. J., Wang H., Journal of Suzhou University, 1995, 25(1), 104—108
	(路建美, 郭永佳, 王红. 苏州大学学报, 1995, 25(1), 104—108)
[13]	Zhu B., Zhang B., Journal of South China University of Technology,1999, 27(12), 100—105
	(朱斌, 张兵. 华南理工大学学报, 1999, 27(12), 100—105)
[14]	Zhang Y. T., Xiao C. F., Chinese Journal of Materials Research,2009, 23(4), 399—404
	(张玉婷, 肖长发. 材料研究学报,2009, 23(4), 399—404)
[15]	Chen X. T., Tang X. D., Ion Exchange and Adsorption, 2005, 21(6), 536—541
	(陈晓婷, 唐旭东. 离子交换与吸附, 2005, 21(6), 536—541)
[16]	Huang Q. S., Weng Z. X., Huang Z. M., Polymer Materials Science and Engineering, 2002, 18(9), 79—82
	(黄岐善, 翁志学, 黄志明. 高分子材料科学与工程, 2002, 18(9), 79—82)
[17]	Wang X. H., Nie M., China Plastics Industry, 2010, 38(7), 14—17
	(王孝华, 聂明. 塑料工业, 2010, 38(7), 14—17)
[18]	Lin J. Y., Shang Y. W., Ding B., Yang J. M., Yu J. Y., Salem S., Marine Pollution Bulletin, 2011, 64(2), 347—352
[19]	Wang J. T., Wang A. Q., Marine Pollution Bulletin, 2013, 69(1/2), 91—96
[20]	Corneliu C., Matei M., Igor C., Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2011, 384(1), 675—684
[21]	Wang Y., Qi H. H., China Non-metallic Mining Industry Herald,2006, 15(2), 25—28
	(王毅, 戚红华. 中国非金属矿工业导刊,2006, 15(2), 25—28)
[22]	Liu X. F., Ye Q. M., Mining Research and Development,2004, 24(2), 34—38
	(刘兴奋, 叶巧明. 矿业研究与开发,2004, 24(2), 34—38)
[23]	Yuan J. H., Sun Y. F., Zeng G. P., Journal of Chemical Industry and Engineering,2010, 31(6), 26—30
	(原金海, 孙有房, 曾广鹏. 化学工业与工程技术,2010, 31(6), 26—30)

Synthesis and Properties of High-oil Absorption Resin Modified with Organic Bentonite^†

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 10

References 23

Related Articles 2

Recommended Articles

Metrics

Comments

[1]	LIU Yun, LI Ting, WANG Yang, DONG Weifu. Preparation of Multi-scale Superhydrophobic Cotton/Polydopamine/Silica Composite for Selective Oil Absorption [J]. Chem. J. Chinese Universities, 2019, 40(8): 1775.
[2]	LIU Bing, XU Wan-Fei, LI Hong, LIU Liu, SHEN Yu-Hua, XIE An-Jian. Super-hydrophobic and Super-oleophilic Properties of Taro Leaves and Their Application [J]. Chem. J. Chinese Universities, 2013, 34(9): 2191.