Binding Thermodynamics of p-Sulfonatocalix[4]arene with Quaternary Ammonium Dications

doi:10.7503/cjcu20120897

Abstract

Abstract:

The stoichiometric ratio, binding modes, complex stability constants and thermodynamic parameters of p-sulfonatocalix[4]arene with three quaternary ammonium dication salts were studied in aqueous buffer solution(pH=7.20) by means of ¹H NMR spectroscopy and microcalorimetrical titration. The results obtained from NMR experiments suggest the 1: 1 stoichiometric ratio with different binding modes between host and guest. The results of the microcalorimetrical titration show that the complex stability constants of p-sulfonatocalix[4]arene with three quaternary ammonium dication salts are more than 10⁵ L/mol. Thermodynamically, the host-guest binding behavior are mainly driven by the favorable enthalpic changes, accompanied by the unfavorable entropic changes.

Key words: Quaternary ammonium dication, p-Sulfonatocalix[4]arene, Thermodynamics

CLC Number:

O625

TrendMD:

LI Zhen-Quan, HU Chun-Xiu, CHENG Yu-Qiao, XU Hui, CAO Xu-Long, SONG Xin-Wang, ZHANG Heng-Yi, LIU Yu. Binding Thermodynamics of p-Sulfonatocalix[4]arene with Quaternary Ammonium Dications[J]. Chem. J. Chinese Universities, 2013, 34(4): 853.

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