Chem. J. Chinese Universities ›› 2013, Vol. 34 ›› Issue (4): 964.doi: 10.7503/cjcu20120632

• Physical Chemistry • Previous Articles     Next Articles

Kinetics and Functional Bacteria Analysis of Dichlorophenol Degradation by Electro-biological Reduction

CAO Zhan-Ping1, ZHANG Jing-Li2, ZHANG Hong-Wei1   

  1. 1. Key Laboratory of Hollow Fiber Membrane Material and Membrane Process, Ministry of Education, Tianjin Polytechnic University, Tianjin 300387, China;
    2. School of Environmental and Municipal Engineering, Tianjin Institute of Urban Construction, Tianjin 300384, China
  • Received:2012-07-06 Online:2013-04-10 Published:2013-03-15

Abstract:

The reductive degradation of dichlorophenol(2,4-DCP) was studied in an electro-biological system(electric-assisted microbial system). The colony structure was analyzed by polymerase chain reaction-single strand conformational polymorphism(PCR-SSCP) and a phylogenetic tree was constructed by 16S rRNA gene clone library. The results show that the dichlorophenol degradation in the electro-biological system conforms to the kinetics characteristics of zero-order reaction. Enterococcus, Pseudomonas and Bacteroidales are the dominant bacteria and play a major role in the electron transfer for the electro-biological system. The reverse electron transfer exists between the electrode, cytochrome c, NAD and the pollutants. A long-range electron transfer process of the multiphase interfaces is achieved between the electrode, bacteria and pollutants.

Key words: Electro-biological system, Electronic reverse transfer, Microbial community, Dichlorophenol, Cytochrome c

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