Third-order Nonlinear Optical Properties of CuInS2 Quantum Dots Doped Glass

doi:10.3969/j.issn.0251-0790.2012.02.004

Abstract

Abstract: CuInS₂ nanocrystals doped sodium borosilicate glass were prepared by employing both sol-gel and atmosphere control methods. Morphology and microstructure of CuInS₂ nanocrystals in the glass were characte-rized by means of X-ray powder diffraction(XRD) and transmission electron microscope(TEM). Femtosecond Z-scan technique was employed to study the third-order nonlinear optical properties of the glass. The results show that CuInS₂ nanocrystals in tetragonal crystal system form uniformly in the glass, and the size of the nanocrystals is about 10 nm. The results of femtosecond Z-scan technique show that the glass exhibits excellent third-order nonlinear optical properties, and the third-order nonlinear optical refractive index γ, absorption coefficient β and susceptibility χ⁽³⁾ of the glass are determined to be 8.57×10^-16 m²/W, 3.74×10^-8 m/W, and 1.95×10^-17 m²/V², respectively.

Key words: CuInS₂ nanocrystal, Sodium borosilicate glass, Sol-gel method, Femtosecond Z-scan technique

CLC Number:

O613.5

TrendMD:

XIANG Wei-Dong, ZHAO Hai-Jun, YANG Xin-Yu, ZHONG Jia-Song, LUO Hong-Yan, GUO Yu-Qing, LIANG Xiao-Juan, YANG Xin-Qi. Third-order Nonlinear Optical Properties of CuInS₂ Quantum Dots Doped Glass[J]. Chem. J. Chinese Universities, 2012, 33(02): 230.

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Third-order Nonlinear Optical Properties of CuInS₂ Quantum Dots Doped Glass

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