镧系金属用于有机反应的研究(Ⅳ)——石墨附载的零价态钐与苯甲酰氯的反应

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (1): 54.

镧系金属用于有机反应的研究(Ⅳ)——石墨附载的零价态钐与苯甲酰氯的反应

刘云山, 江涛, 贝浼智

南京师范大学化学系, 南京 210024

收稿日期:1992-09-13 修回日期:1992-12-02 出版日期:1993-01-24 发布日期:1993-01-24
通讯作者: 贝浼智
基金资助:
国家自然科学基金;江苏省教育委员会自然科学基金

Studies on the Application of Lanthanoid Metals to Organic Reactions (Ⅳ)——The Reaction of Sm(0) on Graphite with PhCOCl

LIU Yun-Shan, JIANG Tao, BEI Mei-Zhi

Department of Chemistry, Nanjing Normal University, Nanjing, 210024

Received:1992-09-13 Revised:1992-12-02 Online:1993-01-24 Published:1993-01-24

摘要/Abstract

关键词: 零价钐, 石墨钾, 苯甲酰氯

Abstract: The zero-valent Sm on graphite has been prepared by the reduction of anhydrous SnCl₃ with potassium graphite (C₈K) in refluxing THFunder a purified nitrogen atmosphere.It showed a greater activity than commercial block Sm metal, and reacted with PhCOCl smoothly at r.t.to give the benzil 1, benzoin 2 and stibenediol dibenzoate 3.Compound 3 is the major product and the cis-form of 3 is the dominant among its geometrical isomers.

Key words: Zero-valent Sm, C₈K, PhCOCl

TrendMD:

刘云山, 江涛, 贝浼智. 镧系金属用于有机反应的研究(Ⅳ)——石墨附载的零价态钐与苯甲酰氯的反应. 高等学校化学学报, 1993, 14(1): 54.

LIU Yun-Shan, JIANG Tao, BEI Mei-Zhi . Studies on the Application of Lanthanoid Metals to Organic Reactions (Ⅳ)——The Reaction of Sm(0) on Graphite with PhCOCl. Chem. J. Chinese Universities, 1993, 14(1): 54.

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