高等学校化学学报 ›› 1997, Vol. 18 ›› Issue (5): 818.

• 论文 • 上一篇    下一篇

聚(丙烯酰胺-丙烯酸)/聚(丙烯酰胺-二甲基二烯丙基氯化铵)分子复合型聚合物驱油剂的增粘作用

淡宜, 王琪   

  1. 成都科技大学高分子研究所, 成都, 610065
  • 收稿日期:1996-07-01 出版日期:1997-05-24 发布日期:1997-05-24
  • 通讯作者: 王琪
  • 作者简介:淡宜, 女, 36岁, 博士研究生, 副教授.
  • 基金资助:

    中国石油天然气总公司中青年创新基金;国家教委博士学科点基金

Studies on Viscosity Enhancement of P(AM-AA)/P(AM-DMDAAC) Complex Used as Polymer Flooding Agent

DAN Yi, WANG Qi   

  1. State Key Laboratory of Polymer Materials Engineering and Polymer Research Institute of Chengdu University of Sci.&, Techn., Chengdu, 610065
  • Received:1996-07-01 Online:1997-05-24 Published:1997-05-24

摘要: 通过Brookfield粘度测定及室内岩心驱油试验评定,研究了聚(丙烯酰胺-丙烯酸)/聚(丙烯酸胺-二甲基二烯丙基氯化铵)[P(AM-AA)/P(AM-DMDAAC)]分子复合型聚合物驱油剂的增粘、抗温、抗盐性及其驱油效果.结果表明:聚合物组成一定时,其复合比影响溶液复合增粘效果;复合型聚合物溶液的抗盐性明显优于P(AM-AA)溶液的抗盐性;多价金属离子的加入是提高溶液抗盐性的有效途径.该驱油剂的最终采收率达61.91%.

关键词: 高分子复合溶液, 聚合物驱油剂, 粘度, 采收率

Abstract: The viscosity enhancement, resistance to temperature and salt, as well as the oil recovery rate of poly (acrylamide-acrylic acid)/poly (acrylamide-dimethyldiallylammoniumchloride) [P (AM-AA)/P (AM-DMDAAC)] intermacromolecular complex used for polymer flooding agent were studied by means of viscosity measurement and simulated enhanced oil recovery test.The experimental results show that when AAmolar content in P(AM-AA) is 27-02%, DMDAACmolar content in P(AM-DMDAAC) is 4-59%, and the weight ratio of P (AM-AA) to P (AM-DMDAAC) is 5O/50, the viscosity of complexed solution gets its maxium, 3.5 times high as that of P (AM-AA) solution.Compared to the constituents,P(AM-AA)/P(AM-DMDAAC) complex solution exhibits better tolerance to temperature and salt.The result of simulated enhanced oil recovery test shows that, using P(AM-AA)/P(AM-DMDAAC) complex as polymer flooding agent, the oil recovery rate could reach 61-91 %, being 11.91 % higher than the rate of 50% reached by water flooding.

Key words: Intermacromolecular complex solution, Polymer flooding agent, Viscosity, Enhanced oil recovery

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