高等学校化学学报

高等学校化学学报 ›› 1997, Vol. 18 ›› Issue (9): 1534.

• 研究快报 • 上一篇    下一篇

球烯C60与锌酞菁形成电荷迁移络合物的研究

陈再鸿, 谢永明, 李娟, 詹梦熊   

  1. 厦门大学化学系, 厦门 361005
  • 收稿日期:1997-01-28 出版日期:1997-09-24 发布日期:1997-09-24
  • 通讯作者: 陈再鸿, 男, 57岁, 副教授.
  • 作者简介:陈再鸿, 男, 57岁, 副教授.
  • 基金资助:

    国家自然科学基金;福建省自然科学基金

Studies on the Formation of Charge Transfer Complex Between Fullerene and Zinc Phthalocyanine

CHEN Zai-Hong, XIE Yong-Ming, LI Juan, ZHAN Meng-Xiong   

  1. Department of Chemstry, Xiamen University, Xiamen 361005
  • Received:1997-01-28 Online:1997-09-24 Published:1997-09-24

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关键词: 球烯, 锌酞菁, 电荷迁移络合物, 光伏效应

Abstract: The system of ZnPc-C60 ln speclal mixed organic solvents has been studled by UVVis, fluorescence and laser Raman spectra. The results prove the existence of a chargetransfer complex (CTC) by the lnteractlon between ZnPc and C60 The molar ratio of ZnPc/C60 in CTCis 2: 1. The formation equilibrium constant(K) was determined at 25 C. Mea-surements of photovoltaic effect show that ZnPc-C60 CTCleads to a rernarkable enhancementof photosensitivity comparing to that of ZnPc.

Key words: Fullerene, Zinc phthalocyanine, Charge transfer complex, Photovoltaic effect

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