一种新型铅钐锡正极板栅合金

高等学校化学学报 ›› 2003, Vol. 24 ›› Issue (9): 1677.

一种新型铅钐锡正极板栅合金

周彦葆, 杨春晓, 马敏, 周伟舫, 柳厚田

复旦大学化学系, 上海 200433

收稿日期:2003-03-25 出版日期:2003-09-24 发布日期:2003-09-24
通讯作者: 柳厚田(1944年出生),男,教授.从事电化学研究.E-mail:htliu@fudan.edu.cn E-mail:htliu@fudan.edu.cn
基金资助:
国家自然科学基金(批准号:20173013,29873013)

A New Pb-Sm-Sn Positive Grid Alloy

ZHOU Yan-Bao, YANG Chun-Xiao, MA Min, ZHOU Wei-Fang, LIU Hou-Tian

Department of Chemistry, Fudan University, Shanghai 200433, China

Received:2003-03-25 Online:2003-09-24 Published:2003-09-24

摘要/Abstract

摘要： 目前,铅钙锡合金已广泛用作阀控式铅酸蓄电池(VRLAB)的板栅材料.由于钙的存在,使铅钙锡合金阳极氧化时易形成高阻抗的阳极腐蚀层,并出现晶间腐蚀,电池循环充放电能力仍不理想.为克服铅钙锡合金作为正极板栅材料的不利因素.

关键词: Pb-Sm-Sn合金, 铅酸蓄电池, 浮充电位, 阳极PbO₂腐蚀层

Abstract: The anodic behavio of Pb-(0. 075%-0. 73%)Sm-0. 63%Sn and Pb-0. 088%Ca-0. 63%Sn alloys in sulfuric acid solution has been studied by using cyclic voltammetry, linear sweep voltammetry and impedance-time curves. The experimental results show that samarium in the Pb-Sm-Sn alloy can inhibit the growth of the anodic corrosion layer(PbO₂) formed on the alloy. Moreover, the evolution of oxygen at the Pb-Sm-Sn alloy electrode is less than that at the Pb-Ca-Sn alloy electrode. 2V-200 A·h VRLA batteries were manufactured by using the above two alloy positive grids separately. he corrosion layers formed on the positive gird surfaces after the life test of the batteries were observed by SEM. The results of the test show that the capacity loss of the battery with the Pb-Sm-Sn positive grids is significantly less than that of the battery with the Pb-Ca-Sn positive grids, and the longer floating charge life of the battery with the Pb-Sm-Sn positive grids is caused by the better corrosion-resistant performance of the Pb-Sm-Sn alloy with the anodic corrosion layer having a finer grain structure.

Key words: Pb-Sm-Sn alloy, Lead-acid battery, Floating charge potential, Anodic PbO₂corrosion layer

中图分类号:

O646.6

TrendMD:

周彦葆, 杨春晓, 马敏, 周伟舫, 柳厚田. 一种新型铅钐锡正极板栅合金. 高等学校化学学报, 2003, 24(9): 1677.

ZHOU Yan-Bao, YANG Chun-Xiao, MA Min, ZHOU Wei-Fang, LIU Hou-Tian . A New Pb-Sm-Sn Positive Grid Alloy. Chem. J. Chinese Universities, 2003, 24(9): 1677.