高等学校化学学报

高等学校化学学报 ›› 2003, Vol. 24 ›› Issue (1): 61.

• 论文 • 上一篇    下一篇

蝉翼藤茎中蔗糖酯成分研究

杨学东1, 刘江云2, 许莉3, 徐丽珍2, 杨世林2   

  1. 1. 清华大学分析中心, 北京 100084;
    2. 中国协和医科大学、中国医学科学院药用植物研究所, 北京 100094;
    3. 北京微量化学研究所色谱研究室, 北京 100091
  • 收稿日期:2001-10-25 出版日期:2003-01-24 发布日期:2003-01-24
  • 通讯作者: 徐丽珍(1942年出生),女,教授,博士生导师.主要从事天然药物与中药的研究与开发.E-mail:xulizh@hotmail.com;杨学东(1964年出生),男,清华大学博士后. E-mail:xulizh@hotmail.com

New Sucrose Esters from Securidaca Inappendiculata

YANG Xue-Dong1, LIU Jiang-Yun2, XU Li3, XU Li-Zhen2, YANG Shi-Lin2   

  1. 1. Analysis Center of Tsinghua University, Beijing 100084, China;
    2. Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing 100094, China;
    3. Analysis Center of Beijing Institute of Microchemistry, Beijing 100091, China
  • Received:2001-10-25 Online:2003-01-24 Published:2003-01-24

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被引次数

17

摘要： 从云南产蝉翼藤(Securidacainappendiculata)茎的乙醇提取物中分离得到3个蔗糖酯类成分.采用化学方法和现代光谱分析技术(包括UV,IR,ESIMS,FABMS,1D和2DNMR等)鉴定其结构分别为β-D-(3,4-O-disinapoyl)fructofuranosyl-α-D-(6-O-sinapoyl)glucopyranoside(1),β-D-(3-O-feruloyl)fructofura-nosyl-α-D-(6-O-sinapoyl)glucopyranoside(2)和β-D-(3-O-feruloyl)fructofuranosyl-α-D-(6-O-feruloyl)gluco-pyranoside(3).其中,化合物3为新的阿魏酸蔗糖酯,命名为蝉翼藤糖酯A(SecurosideA).

关键词: 远志科, 蝉翼藤, 蔗糖酯, 蝉翼藤糖酯A

Abstract: Three sucrose esters, β-D-(3,4-O\%-disinapoyl)fructofuranosyl-α-D-(6-O-sinapoyl)gluco-pyranoside(1), β-D-(3-O-feruloyl)fructofuranosyl-α-D-(6-O-sinapoyl)glucopyrano-side(2), and β-D-(3-O-feruloyl) fructofuranosyl-α-D-(6-O-feruloyl)glucopyranoside(3) were isolated from the stems of Securidaca inappendiculata collected from Yunnan Province. Among them, compound 3 was a new sucrose ester and was named as securoside A . All structures were elucidated on the basis of chemical and spectroscopic evidence, especially 13C, 1M NMR and ESI-MS experiments.

Key words: Polygalaceae, Securidaca inappendiculata, Sucrose esters, Securoside A

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