壬基酚聚氧乙烯醚二聚和三聚表面活性剂的合成及表面性质

高等学校化学学报 ›› 2010, Vol. 31 ›› Issue (7): 1465.

壬基酚聚氧乙烯醚二聚和三聚表面活性剂的合成及表面性质

杨芳, 黎钢, 张松梅, 祁健, 刘荣, 徐念

河北工业大学化工学院, 天津 300130

收稿日期:2009-09-23 出版日期:2010-07-10 发布日期:2010-07-10
通讯作者: 黎钢, 男, 博士, 教授, 主要从事改性高分子及胶体界面化学的研究. E-mail: ligang@hebut.edu.cn
基金资助:
河北省自然科学基金(批准号: B2006000019)资助.

Synthesis and Surface Properties of Nonylphenol Polyoxyethylene Dimeric and Trimeric Nonionic Surfactants

YANG Fang, LI Gang*, ZHANG Song-Mei, QI Jian, LIU Rong, XU Nian

School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

Received:2009-09-23 Online:2010-07-10 Published:2010-07-10
Contact: LI Gang. E-mail: ligang@hebut.edu.cn
Supported by:
河北省自然科学基金(批准号: B2006000019)资助.

摘要/Abstract

摘要：

合成了系列壬基酚聚氧乙烯醚二聚表面活性剂(DNP)和三聚表面活性剂(TNP), 用核磁共振、红外光谱和元素分析等手段对其结构进行了表征, 并用表面张力法和稳态荧光法对DNP和TNP的表面性能进行了研究. 结果表明, 随着氧乙烯(EO)单元数的增长, DNP和TNP的临界胶束浓度(cmc)值逐渐增大; DNP和TNP的cmc值较相应的单体壬基酚聚氧乙烯醚表面活性剂(NP)明显降低, 显示了较高的表面活性、吸附能力和润湿能力.

关键词: 壬基酚聚氧乙烯醚二聚表面活性剂; 壬基酚聚氧乙烯醚三聚表面活性剂; 荧光探针; 临界胶束浓度

Abstract:

To investigate surface properties of oligomeric surfactants, a series of dimeric and trimeric nonionic surfactants of nonylphenol polyoxyethylene ether(DNP and TNP) were synthesized and characterized by ¹H NNR, FTIR and elemental analysis. Surface properties of the DNP and TNP were determined by surface tension method and steady-state fluorescence method, respectively. The experimental results show that critical micelle concentration(cmc) increase with the increasing of oxyethylene(EO) units of the DNP and TNP. The cmc of the DNP and TNP are obviously smaller than that of nonionic surfactant of nonylphenol polyoxyethylene ether(NP), which has exhibited predominant surface activities, adsorption affinities and wet abilities of the DNP and TNP.

Key words: Dimeric nonionic surfactant of nonylphenol polyoxyethylene ether; Trimeric nonionic surfactant of nonylphenol polyoxyethylene ether; Fluorescence probe; Critical micelle concentration(cmc)

TrendMD:

杨芳, 黎钢, 张松梅, 祁健, 刘荣, 徐念. 壬基酚聚氧乙烯醚二聚和三聚表面活性剂的合成及表面性质. 高等学校化学学报, 2010, 31(7): 1465.

YANG Fang, LI Gang*, ZHANG Song-Mei, QI Jian, LIU Rong, XU Nian. Synthesis and Surface Properties of Nonylphenol Polyoxyethylene Dimeric and Trimeric Nonionic Surfactants. Chem. J. Chinese Universities, 2010, 31(7): 1465.

参考文献

[1]Raoul Z.. Adv. Colloid Interface Sci.[J], 2002, 97: 203—251
[2]Alargova R. G., Kochijashky I. I., Sierra M. L., Kwetkat K., Zana R.. J. Colloid Interface Sci.[J], 2001, 235: 119—129
[3]Kunio E., Masaya G., Yoshifumi K.. J. Colloid Interface Sci.[J], 1996, 183: 539—548
[4]Bello C., Bombelli C., Borocci S.. Langmuir[J], 2006, 22: 9333—9338
[5]Hong T., Hui N. X.. Tetrahedron Lett.[J], 2008, 49: 1759—1765
[6]Abe M., Tsubone K., Koike T.. Langmuir[J], 2006, 22: 8293—8297
[7]Wei S., Li M. W., He T.. J. Fluorine Chem.[J], 2008, 129: 267—275
[8]WU Zhang-Feng(吴章锋), XU Xiao-Ming(徐晓明), ZHANG Chun-Yan(张春艳), HAN Guo-Bin(韩国彬). Chem. J. Chinese Universities(高等学校化学学报)[J], 2004, 25(12): 2299—2303
[9]Bello C., Bombelli C., Borocci S.. Langmuir[J] , 2006, 22: 9333—9338
[10]HUANG Bei-Bei(黄贝蓓), XU Xiao-Ming(徐晓明), LI Dong-Hua(李东华), LAN Qin(蓝琴), HAN Guo-Bin(韩国彬). Chem. J. Chinese Universities(高等学校化学学报)[J], 2008, 29(10): 2029—2034
[11]Paul A. F., Matthew W. C., Tim W. D., Algirdas K. S., Chris H. S., Gregory G. W.. J. Colloid Interface Sci.[J], 2004, 275: 649—658
[12]Jolanda M. P., Terpstra K. R., Marc C. A. S.. Langmuir[J], 1997, 13(25): 6857—6860
[13]Wang Y. X., Han Y. C., Huang X., Cao M. W., Wang Y. L.. J. Colloid Interface Sci.[J], 2008, 319: 534—541
[14]JIANG Xiao-Hui(蒋晓慧), ZHOU Li-Mei(周丽梅). Chin. J. Org. Chem.(有机化学)[J], 2004, 24(5): 563—566
[15]Zana R., Levy H., Papoutsi D., Beinert G.. Langmuir[J], 1995, 11(10): 3694—3698
[16]In M., Bec V., Aguerre-Chariol O., Zana R.. Langmuir[J], 2000, 16(1): 141—148
[17]Tomokazu Y., Akiko O., Kunio E.. J. Colloid Interface Sci.[J], 2004, 272: 191—196
[18]Castro M. J. L., Kovensky J., Cirelli F.. Langmuir[J], 2002, 18: 2477—2482
[19]FANG Yun(方云), LIU Xue-Feng(刘雪锋), XIA Yong-Mei(夏咏梅), YANG Yang(杨扬), CAI Kun(蔡琨), XU Ting-Mu(徐廷穆), ZHAO Xian-Ying(赵宪英). Acta Phys.-Chim. Sin.(物理化学学报)[J], 2001, 17(9): 828 —831
[20]Shawn D. W., Li X. F., Ronald E. V.. Langmuir[J], 2003, 19: 3666—3670
[21]Li Z. X., Dong C. C., Thomas R. K.. Langmuir[J], 1999, 15: 4392—4396