NaA沸石离子交换过程的介电弛豫谱研究

高等学校化学学报 ›› 2009, Vol. 30 ›› Issue (9): 1793.

NaA沸石离子交换过程的介电弛豫谱研究

周威^1,2, 赵孔双¹

1. 北京师范大学化学学院, 北京100875;
2. 北京工商大学化学与环境工程学院, 北京100048

收稿日期:2008-11-28 出版日期:2009-09-10 发布日期:2009-09-10
通讯作者: 赵孔双, 男, 博士, 教授, 博士生导师, 主要从事介电弛豫谱理论及应用研究. E-mail: zhaoks@bnu.edu.cn
基金资助:
国家自然科学基金(批准号: 20673014 )资助.

Dielectric Relaxation Spectroscopy Study on NaA Zeolite in the Process of Ion Exchange

ZHOU Wei^1,2, ZHAO Kong-Shuang^1*

1. College of Chemistry, Beijing Normal University, Beijing 100875, China;
2. College of Chemistry and Environmental Engineering, Beijing Technology and Business University, Beijing 100048, China

Received:2008-11-28 Online:2009-09-10 Published:2009-09-10
Contact: ZHAO Kong-Shuang. E-mail: zhaoks@bnu.edu.cn
Supported by:
国家自然科学基金(批准号: 20673014 )资助.

摘要/Abstract

摘要：

在40 Hz~110 MHz频率段对不同Ca²⁺交换度的NaA沸石堆积体系进行了介电测量, 并利用Cole-Cole公式及Hanai方法对介电参数和相参数进行拟合与解析. 结果表明, 随着Ca²⁺交换度的不断增高, 堆积体系的介电增量、弛豫频率、弛豫分布系数以及粒子的电导率均有不同程度的降低, 而粒子的介电常数保持不变. 通过综合分析弛豫变化规律与离子交换度的内在联系发现, 离子交换后Ca²⁺选择六元环占位, 同时六元环和八元环位置的相邻2个Na⁺被置换; 占据六元环的Ca²⁺与八元环位置的Na⁺对沸石粒子的极化贡献等价; Ca²⁺的进入导致沸石孔道内微观电场多样化.

关键词: 介电弛豫谱; NaA 沸石; 离子交换

Abstract:

The dielectric properties of NaA zeolite with different ion exchange degree were measured by DRS in the frequency range from 40 Hz to 110 MHz, and Cole-Cole equation and Hanai method were used to attain the dielectric and phase parameters. The results indicate that the dielectric increment, relaxation time, relaxation time distribution parameter and conductivity of particle decrease with ion exchange degree increasing. At the same time, the dielectric constant of particle is independent on the ion exchange degree. By meaning of comprehensive dielectric analysis, the crystal lattice located by Ca²⁺ is infered to six-ring site, Ca²⁺ at six-ring site and Na⁺ at eight-ring site are equivalent on the contribution to the polarization of zeolite particle, and the electric field becomes various with Ca²⁺ exchange.

Key words: Dielectric relaxation spectroscopy; NaA Zeolite; Ion exchange

TrendMD:

周威, 赵孔双. NaA沸石离子交换过程的介电弛豫谱研究. 高等学校化学学报, 2009, 30(9): 1793.

ZHOU Wei, ZHAO Kong-Shuang*. Dielectric Relaxation Spectroscopy Study on NaA Zeolite in the Process of Ion Exchange. Chem. J. Chinese Universities, 2009, 30(9): 1793.

参考文献

[1]LI Jiao-Yang(李骄阳), ZHAO Kong-Shuang(赵孔双). Chem. J. Chinese Universities(高等学校化学学报)
[J], 2006, 27(12): 2362—2365

[2]ZHAO Kong-Shuang(赵孔双), YA Tian-Qiao(疋田巧), LI Zi-Jie(李子杰), et al.. Chem. J. Chinese Universities(高等学校化学学报)
[J], 2003, 24(5): 850—853

[3]Yang L. K., Zhao K. S.. Langmuir
[J], 2007, 23: 8732—8739

[4]Bai W., Zhao K. S., Asami K.. Colloids Surf. B
[J], 2007, 58: 105—115

[5]Li Y. H., Zhao K. S.. J. Coll. Interface Sci.
[J], 2004, 276: 68—76

[6]Abdoulaye A., Zanchetta J. V.. Micro. Meso. Mater.
[J], 2000, 34: 317—325

[7]Huwe A., Kremer F., Behrens P., et al.. Phys. Rev. Lett.
[J], 1999, 82: 2338—2341

[8]Ohgushi T., Kawanabe Y.. Zeolites
[J], 1994, 14: 356—359

[9]Zhou W., Zhao K. S.. J. Phy. Chem. C
[J], 2008, 112(38): 15015—15021

[10]ZHAO Kong-Shuang(赵孔双). The Means and Application of Dielectric Spectroscopy(介电谱方法及应用)
[M], Beijing: Chemical Industry Press, 2008

[11]Raicu V., Gusbeth C., Anghel D., et al.. Biochim. Biophys. Acta
[J], 1998, 1379: 7—15

[12]Wagner K. W.. Arch. Electrotech.
[J], 1914, 2: 371—387

[13]Hanai T., Koizumi N., Sugano T., et al.. Kolloid-Z
[J], 1960, 171: 20—23

[14]Ohgushi T., Ishimaru K.. Phys.Chem. Chem. Phys.
[J], 2001, 3: 3229—3236

[15]Simon U., Franke M. E.. Micropor. Mesopor. Mater.
[J], 2000, 41: 1—36

[16]Rodriguea C., Perea-Maldonado M. T.. Solid State Ionics
[J], 1997, 95: 231—239

[17]Bordi F., Cametti C., Colly R. H.. J. Phys.: Condens. Matter.
[J], 2004, 16: 1423—1463

[18]Kelemen G., Schon G.. J. Mater. Sci.
[J], 1992, 27: 6036—6040

[19]Rice M. J., Roth W. L.. J. Solid State Chem.
[J], 1972, 4: 294—310

[20]Rao K. S., Prasad D. M., Krishna P. M., et al.. Mat. Sci. Eng. B
[J], 2006, 133: 141—150

[21]Huang W. C., Jian H.. J. Non-Cryst Solids
[J], 1997, 212: 117—125