两个金属铜配位聚合物Cu3(2,2′-bipy)2(C8H4O4)2(C8H5O4)2和Cu(Ⅰ)Cu(Ⅱ)(4,4′-bipy)1.5(C8H4O4)(C8H5O4)混合溶剂热合成及结构与性能研究

高等学校化学学报 ›› 2009, Vol. 30 ›› Issue (9): 1691.

两个金属铜配位聚合物Cu₃(2,2′-bipy)₂(C₈H₄O₄)₂(C₈H₅O₄)₂和Cu(Ⅰ)Cu(Ⅱ)(4,4′-bipy)_1.5(C₈H₄O₄)(C₈H₅O₄)混合溶剂热合成及结构与性能研究

高路¹, 李光华¹, 毕明辉¹, 胡亚微^1,2, 刘晓敏¹, 施展¹, 冯守华¹

1. 吉林大学无机合成与制备化学国家重点实验室, 长春 130012;
2. 清华大学材料科学与工程系, 北京 100084

收稿日期:2009-01-22 出版日期:2009-09-10 发布日期:2009-09-10
通讯作者: 施展, 男, 博士, 教授, 博士生导师, 主要从事无机材料化学研究. E-mail: zshi@mail.jlu.edu.cn; 冯守华, 男, 博士, 教授, 博士生导师, 中国科学院院士, 从事无机合成化学研究. E-mail: shfeng@mail.jlu.edu.cn
基金资助:
国家自然科学基金(批准号: 20631010, 20671040, 20601010)资助.

Mixed Solvothermal Synthesis and Characterization of Two Copper Coordination Polymers: Cu₃(2,2′-bipy)₂(C₈H₄O₄)₂(C₈H₅O₄)₂ and Cu(Ⅰ)Cu(Ⅱ)(4,4′-bipy)_1.5(C₈H₄O₄)(C₈H₅O₄)

GAO Lu¹, LI Guang-Hua¹, BI Ming-Hui¹, HU Ya-Wei^1,2, LIU Xiao-Min¹, SHI Zhan¹*, FENG Shou-Hua¹*

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China;
2. Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

Received:2009-01-22 Online:2009-09-10 Published:2009-09-10
Contact: SHI Zhan. E-mail: zshi@mail.jlu.edu.cn; FENG Shou-Hua. E-mail: shfeng@mail.jlu.edu.cn
Supported by:
国家自然科学基金(批准号: 20631010, 20671040, 20601010)资助.

摘要/Abstract

摘要：

在中温混合溶剂热条件下合成了两个金属铜配位聚合物Cu₃(2,2′-bipy)₂(C₈H₄O₄)₂(C₈H₅O₄)₂和Cu(Ⅰ)Cu(Ⅱ)(4,4′-bipy)_1.5(C₈H₄O₄)(C₈H₅O₄)(bipy=联吡啶, C₈H₄O₄=1,3-间苯二甲酸), 并对其进行了单晶结构解析及相关性能表征. 配合物Cu₃(2,2′-bipy)₂(C₈H₄O₄)₂(C₈H₅O₄)₂(1)晶体属三斜晶系, P1空间群, a=1.03314(4) nm, b=1.08350(3) nm, c=1.15826(4) nm, α=83.104(2)°, β=84.609(2)°, γ=66.125(2)°, Z=1. 配合物Cu(Ⅰ)Cu(Ⅱ)(4,4′-bipy)_1.5(C₈H₄O₄)(C₈H₅O₄)(2)晶体属三斜晶系, P1空间群, a=1.06979(3) nm, b=1.09209(3) nm, c=1.47887(3) nm, α=91.795(2)°, β=93.2460(10)°, γ=118.6170(10)°, Z=2. 通过使用不同的有机碱配体(2,2′-联吡啶和4,4′-联吡啶), 并调节不同有机碱配体的用量, 得到了结构不同的两个目标晶体产物相. 产物均可稳定到300 ℃.

关键词: 铜配位聚合物; 混合溶剂热反应; 晶体结构

Abstract:

Two copper coordination polymers, Cu₃(2,2′-bipy)₂(C₈H₄O₄)₂(C₈H₅O₄)₂(1) and Cu(Ⅰ)Cu(Ⅱ)(4,4′-bipy)_1.5(C₈H₄O₄)(C₈H₅O₄) were hydrothermally synthesized in mixed solvothermal and characterized by single crystal X-ray diffraction. Cu₃(2,2′-bipy)₂(C₈H₄O₄)₂(C₈H₅O₄)₂(1) crystallizes in a triclinic system with space group P1 and cell parameters, a=1.03314(4) nm, b=1.08350(3) nm, c=1.15826(4) nm, α=83.104(2)°, β=84.609(2)°, γ=66.125(2)°, and Z=1. Cu(Ⅰ)Cu(Ⅱ)(4,4′-bipy)_1.5(C₈H₄O₄)(C₈H₅O₄)(2) crystallizes also in a triclinic system with space group P1 and cell parameters, a=1.06979(3) nm, b=1.09209(3) nm, c=1.47887(3) nm, α=91.795(2)°, β=93.2460(10)°, γ=118.6170(10)°, and Z=2. Their syntheses were performed under the similar conditions from different organic alkali ligands 2,2′-bipy and 4,4′-bipy at different concentrations. These changes gave rise to the corresponding change in final crystal structure of products. Both compounds are thermally stable up to 300 ℃.

Key words: Copper coordination polymer; Mixed solvothermal reaction; Crystal structure

TrendMD:

高路, 李光华, 毕明辉, 胡亚微, 刘晓敏, 施展, 冯守华. 两个金属铜配位聚合物Cu₃(2,2′-bipy)₂(C₈H₄O₄)₂(C₈H₅O₄)₂和Cu(Ⅰ)Cu(Ⅱ)(4,4′-bipy)_1.5(C₈H₄O₄)(C₈H₅O₄)混合溶剂热合成及结构与性能研究. 高等学校化学学报, 2009, 30(9): 1691.

GAO Lu, LI Guang-Hua, BI Ming-Hui, HU Ya-Wei, LIU Xiao-Min, SHI Zhan*, ....... Mixed Solvothermal Synthesis and Characterization of Two Copper Coordination Polymers: Cu₃(2,2′-bipy)₂(C₈H₄O₄)₂(C₈H₅O₄)₂ and Cu(Ⅰ)Cu(Ⅱ)(4,4′-bipy)_1.5(C₈H₄O₄)(C₈H₅O₄). Chem. J. Chinese Universities, 2009, 30(9): 1691.

参考文献

[1]Ferey G.. Chem. Mater.[J], 2001, 13(10): 3084—3098
[2]Hagtman P. J., Hagrman D., Zubieta J.. Angew. Chem. Int. Ed.[J], 1999, 38(18): 2638—2684
[3]Cheetham A. K., Ferey G., Loiseau T.. Angew. Chem. Int. Ed.[J], 1999, 38(22): 3268—3294
[4]Eddaoudi M., Moler D. B., LI H., et al.. Acc. Chem. Res.[J], 2001, 34(4): 319—330
[5]Shi Z., Li G. H., Zhang D., et al.. Inorg. Chem.[J], 2003, 42(7): 2357—2361
[6]Zapf P. J., Haushalter R. C., Zubieta J.. Chem. Commun.[J], 1997: 321—322
[7]Halasyamani P. S., Drewitt M. J., O′Hare D.. Chem. Commun.[J], 1997: 867—868
[8]Shi Z., Feng S., Zhang L., et al.. Chem. Mater.[J], 2000, 12(10): 2930—2935
[9]Chen V. Y., Lo F. T., Kao H. M., et al.. Chem. Commun.[J], 2000: 1061—1062
[10]Jiang Y. C., Lai Y. C., Wang S. L., et al.. Inorg. Chem.[J], 2001, 40(21): 5320—5321
[11]Lii K. H., Huang Y. F.. Inorg. Chem.[J], 1999, 38(6): 1348—1350
[12]Huang C. H., Huang L. H., Lii K. H.. Inorg. Chem.[J], 2001, 40(11): 2625—2627
[13]REN Hong(任红), XU Jia-Ning(徐家宁), YU Lian-Xiang(于连香). Chem. J. Chinese Universities(高等学校化学学报)[J], 2007, 28(6): 1014—1017
[14]FANG Qian-Rong(方千荣), ZHU Guang-Shan(朱广山), DING Hong(丁红). Chem. J. Chinese Universities(高等学校化学学报)[J], 2004, 25(12): 2218—2220
[15]Gao L., Zhao B. J., Li G. H., et al.. Inorg. Chem. Commun.[J], 2003, 6(9): 1249—1251
[16]Eddaoudi M., Kim J., Wachter J. B., et al.. J. Am. Chem. Soc.[J], 2001, 123(18): 4368—4369
[17]Vodak D. T., Braun M. E., Kim J., et al.. Chem. Commun.[J], 2001: 2534—2535
[18]Hu M. L., Xu D. J., Cheng D. P.. J. Coord. Chem.[J], 2002, 55(1): 11—16
[19]Madison W. I., SMART, SAINT, Siemens Analytical X-ray Instruments Inc.[CP], 1996
[20]SHELXTL, Version 5.1, Siemens Industrial Automation Inc.[CP], 1997
[21]Brown I. D., Shannon R. D.. Acta Crystallogr.[J], 1973, A29: 266—282
[22]Brown I. D., Altermatt D.. Acta Crystallogr.[J], 1985, B41: 244—247
[23]Tao J., Zhang Y., Tong M. L., et al.. Chem. Commun.[J], 2002, (13): 1342—1343

两个金属铜配位聚合物Cu₃(2,2′-bipy)₂(C₈H₄O₄)₂(C₈H₅O₄)₂和Cu(Ⅰ)Cu(Ⅱ)(4,4′-bipy)_1.5(C₈H₄O₄)(C₈H₅O₄)混合溶剂热合成及结构与性能研究

Mixed Solvothermal Synthesis and Characterization of Two Copper Coordination Polymers: Cu₃(2,2′-bipy)₂(C₈H₄O₄)₂(C₈H₅O₄)₂ and Cu(Ⅰ)Cu(Ⅱ)(4,4′-bipy)_1.5(C₈H₄O₄)(C₈H₅O₄)

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 0

编辑推荐

Metrics

本文评价