铁掺杂钐镓石榴石Sm3Ga5-xFexO12(x=1,2,3,4)可逆热致变色材料的合成与表征

doi:10.7503/cjcu20180606

高等学校化学学报 ›› 2019, Vol. 40 ›› Issue (4): 652.doi: 10.7503/cjcu20180606

铁掺杂钐镓石榴石Sm₃Ga_5-_xFe_xO₁₂(x=1,2,3,4)可逆热致变色材料的合成与表征

刘欢欢¹, 袁龙^1,², 刘景海³, 侯长民¹(), 冯守华¹

1. 吉林大学化学学院, 无机合成与制备化学国家重点实验室, 长春 130012
2. 吉林师范大学功能材料物理与化学教育部重点实验室, 长春 130103
3. 内蒙古民族大学内蒙古自治区纳米碳材料重点实验室, 通辽 028000

收稿日期:2018-08-30 出版日期:2019-04-03 发布日期:2019-01-09
作者简介:
联系人简介: 侯长民, 男, 博士, 副教授, 主要从事无机固体氧化物变色传感材料方面的研究. E-mail: houcm@jlu.edu.cn
基金资助:
吉林大学研究生创新基金(批准号: 2017079)、吉林省科技厅项目(批准号: 20160101326JC)、国家自然科学基金(批准号: 21427802)和内蒙古民族大学开放课题(批准号: MDK2018043)资助.

Preparation and Thermochromic Property of Fe³⁺-doped Sm₃Ga₅ $O 12 †$

LIU Huanhuan¹, YUAN Long^1,², LIU Jinghai³, HOU Changmin^1,^*(), FENG Shouhua¹

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
2. Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Changchun 130103, China
3. Inner Mongolia Key Laboratory of Carbon Nanomaterials, Inner Mongolia University for Nationalities, Tongliao 028000, China

Received:2018-08-30 Online:2019-04-03 Published:2019-01-09
Contact: HOU Changmin E-mail:houcm@jlu.edu.cn
Supported by:
† Supported by the Graduate Innovation Fund of Jilin University, China(No.2017079), the Foundation of Science and Technology Department of Jilin Province, China(No.20160101326JC), the National Natural Science Foundation of China(No.21427802) and the Open Fund of Inner Mongolia University for Nationalities, China(No.MDK2018043).

摘要/Abstract

摘要：

采用传统高温固相法合成了系列Fe掺杂钐镓石榴石Sm₃Ga_5-_xFe_xO₁₂(x=1,2,3,4)可逆热致变色材料, 并通过粉末X射线衍射(XRD)、红外光谱(FTIR)、拉曼光谱(Raman)、扫描电子显微镜(SEM)、 X射线光电子能谱(XPS)及固体紫外光谱分析技术研究了物质的结构及性质. 在室温下, 随着铁掺杂量的增加, 样品的颜色从亮黄绿色逐渐变为深墨绿色, 且随着温度从室温升至500 ℃, 样品的颜色也逐渐变为相应的橘黄色和棕色. 样品在室温下所呈现的黄绿色是源于其在紫色光区域及橙红色光区域内有相应的吸收行为, 且随着温度的升高, 吸收行为持续红移, 样品颜色也随之发生变化.

关键词: 铁掺杂钐镓石榴石, 颜色调控, 热致变色

Abstract:

The reversible thermochromic materials, Fe³⁺-doped Sm₃Ga₅O₁₂, was prepared via high temperature solid state reaction method, and their structure and properties were characterized by X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FTIR), Raman spectroscopy, scanning electron microscopy(SEM), X-ray photoelectron spectroscopy(XPS) and UV-Vis spectroscopy. With the increase of Fe³⁺ doping, the samples’ color gradually changed from bright yellow-green to dark green at room temperature, and when the temperature was increased from room temperature to 500 ℃, the color of the samples gradually turned to orange and brown. The yellow-green color of the sample at room temperature is due to its absorption in the violet region and orange-red region, and continuous red shift of absorption edge is accompanied by changes in color with temperature increasing.

Key words: Fe³⁺-doped Sm₃Ga₅O₁₂, Color tuning, Thermochromism

中图分类号:

O611

TrendMD:

刘欢欢, 袁龙, 刘景海, 侯长民, 冯守华. 铁掺杂钐镓石榴石Sm₃Ga_5-_xFe_xO₁₂(x=1,2,3,4)可逆热致变色材料的合成与表征. 高等学校化学学报, 2019, 40(4): 652.

LIU Huanhuan,YUAN Long,LIU Jinghai,HOU Changmin,FENG Shouhua. Preparation and Thermochromic Property of Fe³⁺-doped Sm₃Ga₅ $O 12 †$ . Chem. J. Chinese Universities, 2019, 40(4): 652.

图/表 10

Fig.1 Photographs(insets) and CIE-Lab parameters at different temperatures of Sm3Ga5-xFexO12[x=1(A), 2(B), 3(C), 4(D)]

Fig.2 Rietveld refinement pattern for XRD patterns of Sm3Ga5-xFexO12[x=1(A), 2(B), 3(C), 4(D)]

Table 1 Refinement results of Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Sample	Space group	Lattice parameter/nm	Volume/nm³	R_wp(%)	R_p(%)
Sm₃Ga₄FeO₁₂	Ia $3 ˉ$ d(230)	1.24672(4)	1.93779	11.13	6.74
Sm₃Ga₃Fe₂O₁₂	Ia $3 ˉ$ d(230)	1.24785(1)	1.94306	10.74	7.15
Sm₃Ga₂Fe₃O₁₂	Ia $3 ˉ$ d(230)	1.24977(0)	1.95205	9.82	6.66
Sm₃GaFe₄O₁₂	Ia $3 ˉ$ d(230)	1.25162(3)	1.96073	10.15	6.68

Table 1 Refinement results of Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Sample	Space group	Lattice parameter/nm	Volume/nm³	R_wp(%)	R_p(%)
Sm₃Ga₄FeO₁₂	Ia $3 ˉ$ d(230)	1.24672(4)	1.93779	11.13	6.74
Sm₃Ga₃Fe₂O₁₂	Ia $3 ˉ$ d(230)	1.24785(1)	1.94306	10.74	7.15
Sm₃Ga₂Fe₃O₁₂	Ia $3 ˉ$ d(230)	1.24977(0)	1.95205	9.82	6.66
Sm₃GaFe₄O₁₂	Ia $3 ˉ$ d(230)	1.25162(3)	1.96073	10.15	6.68

Fig.3 FTIR spectra in the range of 400—4000 cm-1 for Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Fig.4 Raman spectra in the range of 100—800 cm-1 for Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Fig.5 SEM images of Sm3Ga5-xFexO12[x=1(A), 2(B), 3(C), 4(D)]

Fig.6 XPS of Fe2P spectra for Sm3Ga5-xFexO12[x=1(A), 2(B), 3(C), 4(D)]

Fig.7 UV-Vis spectra(Kubelka-Munk transformed) of Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Fig.8 Temperature dependent UV-Vis spectra of Sm3Ga5-xFexO12(x=1, 2, 3, 4)

Table 2 Photographs of the reversible thermochromic cycle experiment

参考文献 33

[1]	Lataste E., Demourgues A., Salmi J., Naporea C., Gaudon M., Dyes and Pigments,2011, 91, 396—403
[2]	Gaudon M., Basly B., Fauque Y., Majimel J., Delville M.H., Inorg. Chem., 2009, 48, 2136—2139
[3]	Gaudon M., Deniard P., Voisin L., Lacombe G., Darnat F., Demourgues A., Perillon J. L., Jobic S., Dyes and Pigments,2012, 95, 344—350
[4]	Day J. H., Chem.Rev., 1963, 63, 65—80
[5]	Salek G., Devoti A., Lataste E., Demourgues A., Garcia A., Jubera V., Gaudon M., J.Luminescence,2016, 179, 189—196
[6]	Gaudon M., Carbonera C., Thiry A. E., Demourgues A., Deniard P., Payen C., Letard J. F., Jobic S., Inorg.Chem.,2007, 46, 10200—10207
[7]	Seeboth A., Lötzsch D., Thermochromic Phenomena in Polymers, Smithers Rapra Technology Limited, Shawbury, 2008
[8]	Sone K., Fukuda K., Inorganic Thermochromism, Springer-Verlag Berlin, Heidelberg, 1987
[9]	Gaudon M., Deniard P., Demourgues A., Thiry A. E., Carbonera C., le Nestour A., Largeteau A., Létard J. F., Jobic S., Adv.Mater.,2007, 19, 3517—3519
[10]	González-Jiménez I. N., Climent E., Torres-Pardo A., Hernando M., Sánchez-Peláez A. E., Fernández-Martínez F., Teresa Fernández Díaz M., González-Calbet J. M., Andrés A., Varela A., Parras M., Inorg.Chem.,2016, 55, 3980—3991
[11]	Serier-Brault H., Thibault L., Legrain M., Deniard P., Rocquefelte X., Leone P., Perillon J. L., Le Bris S., Waku J., Jobic S., Inorg.Chem.,2014, 53, 12378—12383
[12]	Liu H., Yuan L., Qi H., Wang S., Du Y., Zhang Y. M., Hou C. M., Feng S. H., Dyes and Pigments,2017, 145, 418—426
[13]	Yousif A., Som S., Kumar V., Swart H. C., Materials Chemistry and Physics,2015, 166, 167—175
[14]	Haritha P., Dwaraka V. C. S., Linganna K., Babu P., Jayasankar C. K., Lavín V., Venkatramu V., J.Luminescence,2016, 179, 533—538
[15]	Fu Q. P., Liu X. F., Chen Y. J., Hong C. H., Hu X. L., Zhuang N. F., Chen J. Z., J. Alloys Compounds,2016, 660, 471—479
[16]	Fernandez P. G., Moreno M., Aramburu J. A., Inorg.Chem.,2015, 54, 192—199
[17]	Divya S., Rao P. P., Sameera S., Raj A. K. V., Dyes and Pigments,2016, 134, 506—515
[18]	Milanese C., Buscaglia V., Maglia F., Anselmi-Tamburini U., Chem.Mater.,2004, 16, 1232—1239
[19]	Butkute S., Zabiliute A., Skaudzius R., Vitta P., Beganskiene A., Zukauskas A., Kareiva A., J. Sol-Gel Sci.Technol.,2015, 76, 210—219
[20]	Katelnikovas A., Kareiva A., Materials Letters,2008, 62, 1655—1658
[21]	Monteseguro V., Rodríguez-Hernández P., Vilaplana R., Manjón F. J., Venkatramu V., Errandonea D., Lavín V., Muñoz A., J. Phys. Chem.C,2014, 118, 13177—13185
[22]	Monteseguro V., Rathaiah M., Linganna K., Lozano-Gorrín A. D., Hernández-Rodríguez M. A., Martín I. R., Babu P., Rodríguez-Mendoza U. R., Manjón F. J., Muñoz A., Jayasankar C. K., Ven-katramu V., Lavín V., Optical Materials Express,2015, 5, 1661—1673
[23]	Venkatramu V., Giarola M., Mariotto G., Enzo S., Polizzi S., Jayasankar C. K., Piccinelli F., Bettinelli M., Speghini A., Nanotechnology,2010, 21, 175703
[24]	Venkatramu V., Leon-Luis S. F., Rodrıguez-Mendoza U. R., Mon-teseguro V., Manjon F. J., Lozano-Gorrın A. D., Valiente R., Navarro-Urrios D., Jayasankar C. K., Munozd A., Lavin V., J. Mater.Chem.,2012, 22, 13788—13799
[25]	Monteseguro V., Rodriguez-Hernández P., Ortiz H. M., Venka-tramu V., Manjon F. J., Jayasankar C. K., Lavinah V., Munoz A., Phys. Chem. Chem.Phys.,2015, 17, 9454—9464
[26]	Liu H., Yuan L., Wang S., Fang H., Zhang Y., Hou C., Feng S., J. Mater. Chem.C,2016, 4, 10529—10537
[27]	Guo L., Yuan H., Huang K., Yuan L., Liu S., Feng S., J. Solid State Chem.,2011, 184, 1048—1053
[28]	Liu X. R., Hou C. M., Yuan L., Liu S. K., Qin Y. Y., Huang K., Feng S. H.,Chem. J. Chinese Universities,2013, 34(2), 277—283
	(刘宪瑞, 侯长民, 袁龙, 刘绍孔, 秦圆圆, 黄科科, 冯守华. 高等学校化学学报, 2013, 34(2), 277—283)
[29]	Guo L., Yuan H. M., Huang K. K., Yuan L., Liu S. K., Feng S. H., Chem. Res. Chinese Universities,2011, 27(4), 715—719
[30]	Nogales E., Garcia J. A., Mendez B., Piqueras J., Lorenz K., Alves E., J. Phys. D: Appl. Phys.,2008, 41, 065406
[31]	Suchomski C., Reitz C., Sousa C. T., Araujo J. P., Brezesinski T., Chem.Mater.,2013, 25, 2527—2537
[32]	Liu H., Yuan L., Qi H., Du Y., Wang S., Hou C. M., RSC Adv., 2017, 7, 37765—37770
[33]	Wemple S.H., Blank S. L., Seman J. A., Biolsi W. A., Phys. Rev. B: Solid State, 1974, 9, 2134—2144

铁掺杂钐镓石榴石Sm₃Ga_5-_xFe_xO₁₂(x=1,2,3,4)可逆热致变色材料的合成与表征

Preparation and Thermochromic Property of Fe³⁺-doped Sm₃Ga₅ $O 12 †$

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