Co2+/Ni2+共催化高效氧化生物质愈创木酚制备香兰素

doi:10.7503/cjcu20180187

高等学校化学学报 ›› 2018, Vol. 39 ›› Issue (8): 1691.doi: 10.7503/cjcu20180187

Co²⁺/Ni²⁺共催化高效氧化生物质愈创木酚制备香兰素

毛海舫¹, 张博¹, 胡晓钧¹, 蔡娇阳¹, 梅甜甜¹, 刘吉波¹, 张小良²

1. 上海应用技术大学化学与环境工程学院, 上海 201418;
2. 城市建设与安全工程学院, 上海 201418

收稿日期:2018-03-09 修回日期:2018-07-30 出版日期:2018-08-10 发布日期:2018-06-04
通讯作者: 张小良,男,博士,教授,主要从事化工安全方面的研究.E-mail:yyyzxl@126.com;刘吉波,男,博士,讲师,主要从事香料与药物合成工艺及绿色合成技术方面的研究.E-mail:jiboliu@sit.edu.cn E-mail:yyyzxl@126.com;jiboliu@sit.edu.cn
基金资助:
上海市科委地方高校能力建设项目（批准号：15120503700）资助.

High Efficiently co-Catalytic Oxidation Bio-guaiacol to Vanillin by Co²⁺/Ni²⁺

MAO Haifang¹, ZHANG Bo¹, HU Xiaojun¹, CAI Jiaoyang¹, MEI Tiantian¹, LIU Jibo¹, ZHANG Xiaoliang²

1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China;
2. College of Urban Construction and Safety Engineering, Shanghai Institute of Technology, Shanghai 201418, China

Received:2018-03-09 Revised:2018-07-30 Online:2018-08-10 Published:2018-06-04
Supported by:
Supported by the Project of Shanghai Science and Technology Commission, China(No.15120503700).

摘要/Abstract

摘要： 建立了一种碱性条件下过渡金属Co²⁺和Ni²⁺共同参与的催化氧化体系，用于高效制备香兰素.该体系能够在0.035 MPa的O₂分压下将多种生物质愈创木酚高效快速地转化为香兰素，转化率均约为90%.通过密度泛函理论构筑了反应物的分子模型，并通过对取代基α碳和β碳的电子云密度进行分析，验证了烷基取代基碳的反应能力.同时，考虑到反应过程中存在封闭的CH₃OH-O₂体系气体环境，进一步对反应条件进行了模拟安全实验，得出该体系90℃发生爆炸的最低氧压力为0.037 MPa，确保了实验的安全进行，也对将来进行工业化生产具有较强的指导意义.

关键词: 愈创木酚, 香兰素, CH₃OH-O₂体系, 安全性检测

Abstract: A catalytic oxidation system involving transition metals Co²⁺ and Ni²⁺ was studied for high-efficiency vanillin preparation under alkaline conditions. The catalytic system could efficiently convert a variety of biomass guaiacol into vanillin rapidly in low O₂ pressure. Using the density functional theory(DFT), the molecular model of the reactants was constructed and the reaction activity of the substituent group was verified by analyzing the electron cloud density of α-carbon and β-carbon. Furthermore, considering the reaction taken place in a closed environment with the presence of CH₃OH and O₂ under high temperature and pressure, the safety experiments were employed to ensure the experiment carrying out under safety condition. It also had important guiding significance to industrial production in the future.

Key words: Guaiacol, Vanillin, CH₃OH-O₂ system, Safety examination

中图分类号:

O625

TrendMD:

毛海舫, 张博, 胡晓钧, 蔡娇阳, 梅甜甜, 刘吉波, 张小良. Co²⁺/Ni²⁺共催化高效氧化生物质愈创木酚制备香兰素. 高等学校化学学报, 2018, 39(8): 1691.

MAO Haifang, ZHANG Bo, HU Xiaojun, CAI Jiaoyang, MEI Tiantian, LIU Jibo, ZHANG Xiaoliang. High Efficiently co-Catalytic Oxidation Bio-guaiacol to Vanillin by Co²⁺/Ni²⁺. Chem. J. Chinese Universities, 2018, 39(8): 1691.

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Co²⁺/Ni²⁺共催化高效氧化生物质愈创木酚制备香兰素

High Efficiently co-Catalytic Oxidation Bio-guaiacol to Vanillin by Co²⁺/Ni²⁺

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