高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (S1): 342.

• Molecular Spectroscopy • 上一篇    下一篇

Electrogenerated Ru(bpy)32+ Chemiluminescent Reactions with Amines Compounds

CHEN Xi, CHEN Wei, JIA Li, WANG Xiao-Ru   

  1. Department of Chemistry and the Key Laboratory of Analytical Sciences of MOE, Xiamen University, Xiamen 361005, P. R. China
  • 出版日期:1999-12-31 发布日期:1999-12-31
  • 基金资助:

    The authors thank the National Natural Scientific Foundation of China for the supports of this research (No.29877022).

Electrogenerated Ru(bpy)32+ Chemiluminescent Reactions with Amines Compounds

CHEN Xi, CHEN Wei, JIA Li, WANG Xiao-Ru   

  1. Department of Chemistry and the Key Laboratory of Analytical Sciences of MOE, Xiamen University, Xiamen 361005, P. R. China
  • Online:1999-12-31 Published:1999-12-31
  • Supported by:

    The authors thank the National Natural Scientific Foundation of China for the supports of this research (No.29877022).

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摘要：

The chemiluminescence (CL) using Ru(bpy)32+ has become an attractive detection method for biochemical substances,such as amines or amino acids. The sensitivities for their determinations are limited because pre-electrolysis for Ru(bpy)32+ to Ru(bpy)33+ is necessary for CL determination, and Ru(bpy)33+ is easily reduced by co-exist substances in buffer solution. Recently, we developed an electrogenerated chemiluminescence (ECL) flow system for Ru(bpy)32+ in-situ applications.

Abstract:

The chemiluminescence (CL) using Ru(bpy)32+ has become an attractive detection method for biochemical substances,such as amines or amino acids. The sensitivities for their determinations are limited because pre-electrolysis for Ru(bpy)32+ to Ru(bpy)33+ is necessary for CL determination, and Ru(bpy)33+ is easily reduced by co-exist substances in buffer solution. Recently, we developed an electrogenerated chemiluminescence (ECL) flow system for Ru(bpy)32+ in-situ applications.

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